发明名称 |
Naphtha reforming catalyst and preparation method thereof |
摘要 |
A naphtha reforming catalyst, comprising an alumina support and following components with the content calculated on the basis of the support: VIII group metal 0.1-2.0% by weight, VIIB group metal 0.1-3.0% by weight, sulfate ion 0.45-3.0% by weight, and halogen 0.5-3.0% by weight. The catalyst is used in a naphtha reforming reaction without presulfurization and has a high aromatization activity and a selectivity. |
申请公布号 |
US9623403(B2) |
申请公布日期 |
2017.04.18 |
申请号 |
US201514831526 |
申请日期 |
2015.08.20 |
申请人 |
CHINA PETROLEUM & CHEMICAL CORPORATION;RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC |
发明人 |
Zhang Daqing;Zang Gaoshan;Zhang Yuhong;Wang Jiaxin;Wang Tao |
分类号 |
B01J23/40;B01J23/42;B01J23/44;B01J27/10;B01J37/04;B01J37/08;B01J37/06;B01J32/00;B01J27/13;B01J27/053;B01J35/10;B01J37/03;B01J21/04;B01J23/656;B01J37/00;B01J37/02;B01J23/63 |
主分类号 |
B01J23/40 |
代理机构 |
Novick, Kim & Lee, PLLC |
代理人 |
Novick, Kim & Lee, PLLC ;Xue Allen |
主权项 |
1. A naphtha reforming catalyst, comprising: a sulfate ion-containing alumina support, and a VIII group metal of 0.1-2.0% by weight, a VIIB group metal of 0.1-3.0% by weight, and a halogen of 0.5-3.0% by weight supported on the alumina support,
wherein the alumina support comprises sulfate ions of 0.45-3.0% by weight and a sodium content of 0.008-0.03% by weight, wherein the weight percentages are calculated based on a weight of the alumina support, and wherein, in said catalyst, a ratio of a pore volume of pores with a pore radius between 3 nm and 10 nm to a total pore volume is from 60% to 85%, a ratio of a pore volume of pores with a pore radius smaller than 3 nm to the total pore volume is not more than 36%, and a ratio of a pore volume of pores with a pore radius larger than 10 nm to the total pore volume is more than 2%. |
地址 |
Beijing CN |