Polycarbonate resin composition and molded article

摘要

Provided is a polycarbonate-based resin composition, including, with respect to 100 parts by mass of (A) a resin mixture formed of 30 to 100 mass % of a polycarbonate-polyorganosiloxane copolymer (A-1) having a structural unit represented by the general formula (I) and a structural unit represented by the general formula (II), and having an average number of repetitions n of an organosiloxane constituent unit in the general formula (II) of 50 to 500, and 0 to 70 mass % of an aromatic polycarbonate (A-2) except the copolymer (A-1), 1 to 5.5 parts by mass of (B) a polyorganosiloxane-acrylic composite rubber, the composition having a viscosity-average molecular weight of 17,000 to 23,000. Also provided is a molded article thereof.;

主权项

1. A polycarbonate-based resin composition, comprising, with respect to 100 parts by mass of (A) a resin mixture formed of 30 to 100 mass % of a polycarbonate-polyorganosiloxane copolymer (A-1) having a structural unit represented by the general formula (I) and a structural unit represented by the general formula (II), and having an average number of repetitions n of an organosiloxane constituent unit in the general formula (II) of 50 to 500, and 0 to 70 mass % of an aromatic polycarbonate (A-2) except the copolymer (A-1), 1.5 to 4.5 parts by mass of (B) a polyorganosiloxane-acrylic composite rubber, the composition having a viscosity-average molecular weight of from 17000 to 23000: wherein R1 and R2 each independently represent an alkyl group or alkoxy group having 1 to 6 carbon atoms, X represents a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, —S—, —SO—, —SO2—, —O—, or —CO—, a and b each independently represent an integer of 0 to 4, R3 to R6 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms, Y represents an organic residue containing an aliphatic or aromatic moiety, and n represents an average number of repetitions.