| 主权项 |
1. A process for the preparation of an [M(X)2(L)m(L2)] complex, the process comprising the step of:
reacting an [M(X)2(L)3] complex with a phosphorus ligand L1 and a bidentate N,N ligand L2 in a ketone solvent to form the [M(X)2(L1)m(L2)] complex; wherein, M is ruthenium or osmium; X is an anionic ligand; L is a monodentate phosphorus ligand; L is a monodentate phosphorus ligand which is different to L, or a bidentate phosphorus ligand; m is 1 or 2, wherein, when m is 1, L1 is a bidentate phosphorus ligand; when m is 2, each L1 is a monodentate phosphorus ligand; and L2 is a bidentate N,N ligand comprising a nitrogen-containing heteroaryl group and an amino group. |
