| 主权项 |
1. A Metal-Organic Framework (MOF) comprising a plurality of linked M-O-L Secondary Building Units (SBUs), wherein M is a metal, metal ion, or metal containing complex; O is an oxygen atom of a carboxylate based linking cluster; and L is an organic linking ligand comprising one or more structures of any one of Formula I-V:wherein,
A1-A3 are independently a C, N, O, or S; X1-X3 are independently selected from H, D, functional group (“FG”), optionally substituted (C1-C20)alkyl, optionally substituted (C1-C19)heteroalkyl, optionally substituted (C1-C20)alkenyl, optionally substituted (C1-C19)heteroalkenyl, optionally substituted (C1-C19)alkynyl, optionally substituted (C1-C19)heteroalkynyl, optionally substituted (C1-C19)cycloalkyl, optionally substituted (C1-C19)cycloalkenyl, optionally substituted aryl, optionally substituted heterocycle, optionally substituted mixed ring system, wherein one or more adjacent R groups can be linked together to form one or more optionally substituted rings selected from cycloalkyl, cycloalkenyl, heterocycle, aryl, and mixed ring system; and R1-R51 are independently selected from H, D, FG, optionally substituted (C1-C20)alkyl, optionally substituted (C1-C19)heteroalkyl, optionally substituted (C1-C20)alkenyl, optionally substituted (C1-C19)heteroalkenyl, optionally substituted (C1-C19)alkynyl, optionally substituted (C1-C19)heteroalkynyl, optionally substituted (C1-C19)cycloalkyl, optionally substituted (C1-C19)cycloalkenyl, optionally substituted aryl, optionally substituted heterocycle, optionally substituted mixed ring system, wherein one or more adjacent R groups can be linked together to form one or more optionally substituted rings selected from the group comprising cycloalkyl, cycloalkenyl, heterocycle, aryl, and mixed ring system; wherein the SBUs of the MOF optionally comprises one or more pendant linkers and/or one or more modulators; and wherein the MOF is characterized by having a large number of adsorption sites per unit of volume. |
