2-(HET)ARYL-SUBSTITUTED FUSED BICYCLIC HETEROCYCLE DERIVATIVES AS PESTICIDES

摘要

The invention relates to novel compounds of the formula (I);;in which the R1, R2a, R2b, R3, A1, A2, A3, A4, A5 and n radicals are each as defined above,

to the use thereof as acaricides and/or insecticides for controlling animal pests and to processes and intermediates for preparation thereof.

主权项

1. Compound of formula (I) in which A1 is nitrogen, ═N+—O− or ═C—R4, A2 is —N—R5, oxygen or sulphur, A3 is oxygen, A4 is nitrogen, ═N+—O− or ═C—R4, A5 is ═C—H, R1 is (C1-C6)alkyl, (C1-C6)haloalkyl, (C1-C6)cyanoalkyl, (C2-C6)hydroxyalkyl,
(C1-C6)alkoxy-(C1-C6)alkyl, (C1-C6)haloalkoxy-(C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkenyloxy-(C1-C6)alkyl, (C2-C6)haloalkenyloxy-(C1-C6)alkyl, (C2-C6)haloalkenyl, (C2-C6)cyanoalkenyl, (C2-C6)alkynyl, (C2-C6)alkynyloxy-(C1-C6)alkyl, (C2-C6)haloalkynyloxy-(C1-C6)alkyl, (C2-C6)haloalkynyl, (C2-C6)cyanoalkynyl, (C3-C8)cycloalkyl, (C3-C8)cycloalkyl-(C3-C8)cycloalkyl, (C1-C6)alkyl-(C3-C8)cycloalkyl, halo(C3-C8)cycloalkyl, amino, (C1-C6)alkylamino, di(C1-C6)alkylamino, (C3-C8)cycloalkylamino, (C1-C6)alkylcarbonylamino, (C1-C6)alkylthio-(C1-C6)alkyl, (C1-C6)haloalkylthio-(C1-C6)alkyl, (C1-C6)alkylsulphinyl-(C1-C6)alkyl, (C1-C6)haloalkylsulphinyl-(C1-C6)alkyl, (C1-C6)alkylsulphonyl-(C1-C6)alkyl, (C1-C6)haloalkylsulphonyl-(C1-C6)alkyl, (C1-C6)alkoxy-(C1-C6)alkylthio-(C1-C6)alkyl, (C1-C6)alkoxy-(C1-C6)alkylsulphinyl-(C1-C6)alkyl, (C1-C6)alkoxy-(C1-C6)alkylsulphonyl-(C1-C6)alkyl, (C1-C6)alkylcarbonyl-(C1-C6)alkyl, (C1-C6)haloalkylcarbonyl-(C1-C6)alkyl, (C1-C6)alkoxycarbonyl-(C1-C6)alkyl, (C1-C6)haloalkoxycarbonyl-(C1-C6)alkyl, (C1-C6)alkylsulphonylamino, aminosulphonyl-(C1-C6)alkyl, (C1-C6)alkylaminosulphonyl-(C1-C6)alkyl, di(C1-C6)alkylaminosulphonyl-(C1-C6)alkyl,  or is (C1-C6)alkyl, (C1-C6)alkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C8)cycloalkyl, each of which is mono- or polysubstituted identically or differently by aryl, hetaryl or heterocyclyl, where aryl, hetaryl or heterocyclyl may each independently be mono- or polysubstituted identically or differently by halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, aminosulphonyl, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C1-C6)haloalkoxy, (C1-C6)alkylthio, (C1-C6)alkylsulphinyl, (C1-C6)alkylsulphonyl, (C1-C6)alkylsulphimino, (C1-C6)alkylsulphimino-(C1-C6)alkyl, (C1-C6)alkylsulphimino-(C2-C6)alkylcarbonyl, (C1-C6)alkylsulphoximino, (C1-C6)alkylsulphoximino-(C1-C6)alkyl, (C1-C6)alkylsulphoximino-(C2-C6)alkylcarbonyl, (C1-C6)alkoxycarbonyl, (C1-C6)alkylcarbonyl, (C3-C6)trialkylsilyl or benzyl, or R1 is aryl, hetaryl or heterocyclyl, each of which is mono- or polysubstituted identically or differently by halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, (C1-C6)alkyl, (C3-C8)cycloalkyl, (C1-C6)-alkoxy, (C1-C6)haloalkyl, (C1-C6)haloalkoxy, (C1-C6)alkylthio, (C1-C6)alkylsulphinyl, (C1-C6)alkylsulphonyl, (C1-C6)alkylsulphimino, (C1-C6)alkylsulphimino-(C1-C6)alkyl, (C1-C6)alkylsulphimino-(C2-C6)alkylcarbonyl, (C1-C6)alkylsulphoximino, (C1-C6)alkylsulphoximino-(C1-C6)alkyl, (C1-C6)alkylsulphoximino-(C2-C6)alkylcarbonyl, (C1-C6)alkoxycarbonyl, (C1-C6)alkylcarbonyl, (C3-C6)trialkylsilyl, (═O) (only in the case of heterocyclyl) or (═O)2 (only in the case of heterocyclyl), R2a, R2b, R3 and R4 are each independently hydrogen, cyano, halogen, nitro, acetyl, hydroxyl, amino, SCN, tri-(C1-C6)alkylsilyl, (C3-C8)cycloalkyl, (C3-C8)cycloalkyl-(C3-C8)cycloalkyl, (C1-C6)alkyl-(C3-C8)cycloalkyl, halo(C3-C8)cycloalkyl, (C1-C6)alkyl, (C1-C6)haloalkyl, (C1-C6)cyanoalkyl, (C1-C6)hydroxyalkyl, hydroxycarbonyl-(C1-C6)-alkoxy, (C1-C6)alkoxycarbonyl-(C1-C6)alkyl, (C1-C6)alkoxy-(C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)haloalkenyl, (C2-C6)cyanoalkenyl, (C2-C6)alkynyl, (C2-C6)haloalkynyl, (C2-C6)cyanoalkynyl, (C1-C6)alkoxy, (C1-C6)haloalkoxy, (C1-C6)cyanoalkoxy, (C1-C6)alkoxycarbonyl-(C1-C6)alkoxy, (C1-C6)alkoxy-(C1-C6)alkoxy, (C1-C6)alkylhydroxyimino, (C1-C6)alkoxyimino, (C1-C6)alkyl-(C1-C6)alkoxyimino, (C1-C6)haloalkyl-(C1-C6)alkoxyimino, (C1-C6)alkylthio, ((C1-C6))haloalkylthio, (C1-C6)alkoxy-(C1-C6)alkylthio, ((C1-C6))alkylthio-((C1-C6))alkyl, (C1-C6)alkylsulphinyl, (C1-C6)haloalkylsulphinyl, (C1-C6)alkoxy-(C1-C6)alkylsulphinyl, (C1-C6)alkylsulphinyl-(C1-C6)alkyl, (C1-C6)alkylsulphonyl, (C1-C6)haloalkylsulphonyl, (C1-C6)alkoxy-(C1-C6)alkylsulphonyl, (C1-C6)alkylsulphonyl-(C1-C6)alkyl, (C1-C6)alkylsulphonyloxy, (C1-C6)alkylcarbonyl, (C1-C6)alkylthiocarbonyl, (C1-C6)haloalkylcarbonyl, (C1-C6)alkylcarbonyloxy, (C1-C6)alkoxycarbonyl, (C1-C6)haloalkoxycarbonyl, aminocarbonyl, (C1-C6)alkylaminocarbonyl, (C1-C6)alkylaminothiocarbonyl, di(C1-C6)alkylaminocarbonyl, di(C1-C6)alkylaminothiocarbonyl, (C2-C6)alkenylaminocarbonyl, di(C2-C6)-alkenylaminocarbonyl, (C3-C8)cycloalkylaminocarbonyl, (C1-C6)alkylsulphonylamino, (C1-C6)alkylamino, di(C1-C6)alkylamino, aminosulphonyl, (C1-C6)alkylaminosulphonyl, di(C1-C6)alkylaminosulphonyl, (C1-C6)alkylsulphoximino, aminothiocarbonyl, (C1-C6)alkylaminothiocarbonyl, di(C1-C6)alkylaminothiocarbonyl, (C3-C8)cycloalkylamino, NHCO—(C1-C6)alkyl ((C1-C6)alkylcarbonylamino), is aryl or hetaryl, each of which is mono- or polysubstituted identically or differently, where (in the case of hetaryl) at least one carbonyl group may optionally be present and/or where possible substituents in each case are as follows: cyano, carboxyl, halogen, nitro, acetyl, hydroxyl, amino, SCN, tri-(C1-C6)alkylsilyl, (C1-C6)alkyl, (C1-C6)haloalkyl, (C1-C6)cyanoalkyl, (C1-C6)hydroxyalkyl, hydroxycarbonyl-(C1-C6)-alkoxy, (C1-C6)alkoxycarbonyl-(C1-C6)alkyl, (C1-C6)alkoxy-(C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)haloalkenyl, (C2-C6)cyanoalkenyl, (C2-C6)alkynyl, (C2-C6)haloalkynyl, (C2-C6)cyanoalkynyl, (C1-C6)alkoxy, (C1-C6)haloalkoxy, (C1-C6)cyanoalkoxy, (C1-C6)alkoxycarbonyl-(C1-C6)alkoxy, (C1-C6)alkoxy-(C1-C6)alkoxy, (C1-C6)alkylhydroxyimino, (C1-C6)alkoxyimino, (C1-C6)alkyl-(C1-C6)alkoxyimino, (C1-C6)haloalkyl-(C1-C6)alkoxyimino, (C1-C6)alkylthio, ((C1-C6))haloalkylthio, (C1-C6)alkoxy-(C1-C6)alkylthio, (C1-C6)alkylthio-(C1-C6)alkyl, (C1-C6)alkylsulphinyl, (C1-C6)haloalkylsulphinyl, (C1-C6)alkoxy-(C1-C6)alkylsulphinyl, (C1-C6)alkylsulphinyl-(C1-C6)alkyl, (C1-C6)alkylsulphonyl, (C1-C6)haloalkylsulphonyl, (C1-C6)alkoxy-(C1-C6)alkylsulphonyl, (C1-C6)alkylsulphonyl-(C1-C6)alkyl, (C1-C6)alkylsulphonyloxy, (C1-C6)alkylcarbonyl, (C1-C6)haloalkylcarbonyl, (C1-C6)alkylcarbonyloxy, (C1-C6)alkoxycarbonyl, (C1-C6)haloalkoxycarbonyl, aminocarbonyl, (C1-C6)alkylaminocarbonyl, di(C1-C6)alkylaminocarbonyl, (C2-C6)alkenylaminocarbonyl, di(C2-C6)-alkenylaminocarbonyl, (C3-C8)cycloalkylaminocarbonyl, (C1-C6)alkylsulphonylamino, (C1-C6)alkylamino, di(C1-C6)alkylamino, aminosulphonyl, (C1-C6)alkylaminosulphonyl, di(C1-C6)alkylaminosulphonyl, (C1-C6)alkylsulphoximino, aminothiocarbonyl, (C1-C6)alkylaminothiocarbonyl, di(C1-C6)alkylaminothiocarbonyl, (C3-C8)cycloalkylamino, R5 is (C1-C6)alkyl, (C1-C6)haloalkyl, (C1-C6)cyanoalkyl, (C1-C6)hydroxyalkyl, (C1-C6)alkoxy-(C1-C6)alkyl, ((C1-C6))haloalkoxy-((C1-C6))alkyl, (C2-C6)alkenyl, (C2-C6)alkenyloxy-(C1-C6)alkyl, (C2-C6)haloalkenyloxy-((C1-C6))alkyl, (C2-C6)haloalkenyl, (C2-C6)cyanoalkenyl, (C2-C6)alkynyl, (C2-C6)alkynyloxy-(C1-C6)alkyl, (C2-C6)haloalkynyloxy-((C1-C6))alkyl, (C2-C6)haloalkynyl, (C2-C6)cyanoalkynyl, (C3-C8)cycloalkyl, (C3-C8)cycloalkyl-(C3-C8)cycloalkyl, (C1-C6)alkyl-(C3-C8)cycloalkyl, halo(C3-C8)cycloalkyl, (C1-C6)alkylthio-(C1-C6)alkyl, (C1-C6)haloalkylthio-(C1-C6)alkyl, (C1-C6)alkylsulphinyl-(C1-C6)alkyl, (C1-C6)haloalkylsulphinyl-(C1-C6)alkyl, (C1-C6)alkylsulphonyl-(C1-C6)alkyl, (C1-C6)haloalkylsulphonyl-(C1-C6)alkyl, (C1-C6)alkoxy-(C1-C6)alkylthio-(C1-C6)alkyl, (C1-C6)alkoxy-(C1-C6)alkylsulphinyl-(C1-C6)alkyl, (C1-C6)alkoxy-(C1-C6)alkylsulphonyl-(C1-C6)alkyl, (C1-C6)alkylcarbonyl-(C1-C6)alkyl, (C1-C6)haloalkylcarbonyl-(C1-C6)alkyl, (C1-C6)alkoxycarbonyl-(C1-C6)alkyl, (C1-C6)haloalkoxycarbonyl-(C1-C6)alkyl, aminocarbonyl-(C1-C6)alkyl, (C1-C6)alkylamino-(C1-C6)alkyl, di(C1-C6)alkylamino-(C1-C6)alkyl or (C3-C8)cycloalkylamino-(C1-C6)alkyl, n is 0, 1 or 2.