发明名称 |
CATHODE ACTIVE MATERIAL, LITHIUM SECONDARY BATTERY HAVING SAME, AND METHOD FOR PREPARING SAME |
摘要 |
The present invention relates to a cathode active material, a lithium secondary battery having the same, and a method for preparing the same, and the purpose of the present invention is to provide battery properties and thermal stability under a high temperature environment even if the Ni content of M in LiMO2(M=Ni, Co, Ti, Zr, etc.) of layered oxide is increased to 65% or more. The present invention provides a cathode active material for a lithium secondary battery which is represented by chemical formula 1 below and is obtained by substituting a part of Ni, Co and Mn for a dissimilar metal (M) through heat treatment with a lithium source after coating the dissimilar metal (M) on the surface of a transition metal precursor comprising Ni, Co and Mn.;LiNiaCobMncMdO2 [Chemical Formula 1];(0.6<a≦0.9, 0<d≦0.1, a+b+c+d=1, M represents at least one metal element selected from the group consisting of Ti, Al, Mg, Fe, Cu, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si and Zr.) |
申请公布号 |
US2017077514(A1) |
申请公布日期 |
2017.03.16 |
申请号 |
US201415123618 |
申请日期 |
2014.09.12 |
申请人 |
KOREA ELECTRONICS TECHNOLOGY INSTITUTE |
发明人 |
Cho Woosuk;Kim Jeomsoo;Song Junho;Yim Taeeun;Woo Sanggil;Kim Youngjun;Lee Kowoon |
分类号 |
H01M4/525;C01G23/047;C01G53/00;H01M4/505;H01M10/0525 |
主分类号 |
H01M4/525 |
代理机构 |
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代理人 |
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主权项 |
1. A cathode active material for lithium secondary batteries which is represented by Chemical Formula 1 below and is obtained by coating a dissimilar metal (M) on a surface of a transition metal precursor comprising Ni, Co and Mn and then heat-treating the transition metal precursor together with a lithium source so that a portion of Ni, Co and Mn is substituted with the dissimilar metal (M):
LiNiaCobMncMdO2 [Chemical Formula 1] wherein 0.6<a≦0.9, 0<d≦0.1, a+b+c+d=1, and M represents one or more metal elements selected from the group consisting of Ti, Al, Mg, Fe, Cu, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, and Zr. |
地址 |
Seongnam-si, Gyeonggi-do KR |