摘要 |
Disclosed herein are methods of making polymerizable resins containing a 1,3,5-hexahydro-1,3,5-triazine moiety and dental compositions comprising such novel hydrolytically-stable, polymerizable resins derived from a 1,3,5-hexahydro-1,3,5-triazine. |
主权项 |
1. A method of forming a hydrolytically-stable, water-soluble polymerizable resin containing a 1,3,5-hexahydro-1,3,5-triazine moiety, the method comprising:
reacting the 1,3,5-hexahydro-1,3,5-triazine moiety in the presence of a Michael donor under conditions selected to yield mono-substituted and di-substituted 1,3,5-hexahydro-1,3,5-triazine resin present in a combined amount that is greater than a combined amount of tri-substituted 1,3,5-hexahydro-1,3,5-triazine and unreacted 1,3,5-hexahydro-1,3,5-triazine moiety; wherein the Michael donor is selected from the group consisting of a secondary amine and a thiol. |