Method for forming an insert injection-molded article exhibiting improved resistance to heat shock utilizing a specifically defined polybutylene terephthalate composition

摘要

The present invention provides a polybutylene terephthalate resin composition, having performance of high durability and the like in a cold cycle environment, and having high strength. Specifically, relative to 100 parts by weight of a polybutylene terephthalate resin (A) having 30 meq/kg or less of the amount of terminal carboxyl groups, there are added a carbodiimide compound (B) in an amount of 0.3 to 1.5 equivalents of the carbodiimide functional group when the amount of carboxyl terminal group in the polybutylene terephthalate resin (A) is set as 1, 20 to 100 parts by weight of a fibrous filler (C), and 5 to 15 parts by weight of an elastomer (D).

主权项

1. A method of manufacturing an insert injection-molded article wherein the injected portion thereof is a polybutylene id="REI-00001" date="20170228" terepththalateid="REI-00001" id="REI-00002" date="20170228" terephthalate id="REI-00002" composition formed by blending a composition in the absence of an aromatic polyvalent carboxylic acid esters, the composition comprising:
100 parts by weight of a polybutylene terephthalate resin (A) having 30 meq/kg or less of terminal carboxyl groups with a carbodiimide compound (B) in an amount of 0.8 to 1.2 equivalents of the carbodiimide functional group when the amount of terminal carboxyl groups in the polybutylene terephthalate resin (A) is set as 1, wherein the carbodiimide is selected from the group consisting of di-2,6-dimethylphenyl carbodiimide, poly(4,4′-diphenylmethane carbodiimide), poly(phenylene carbodiimide), and poly(triisopropylphenylene carbodiimide); 20 to 100 parts by weight of a fibrous filler (C); and 5 to 15 parts by weight of an elastomer (D) selected from the group consisting of styrene-based thermoplastic elastomer, a grafted olefin-based thermoplastic elastomer, a core-shell elastomer composed mainly of an acrylic-based rubber, a polyester-based thermoplastic elastomer, and mixtures thereof; wherein said composition displays good flowability as evidenced by a melt viscosity of 300 Pa•s or less at a temperature of 260° C. and a shear rate of 1000 sec−1 in accordance with ISO 11443, and injecting said polybutylene terephthalate composition while molten into a mold including a metal insert to form an insert injection-molded article exhibiting improved resistance to heat shock and wherein (A) and (B) are selected and provided in said composition in concentrations so that 0.5 to 1.5 equivalents of carbodiimide functional groups are present per each carboxyl functional group of (A) and wherein (A), (B), (C) and (D) are provided in said composition within the specified ranges so as to facilitate the expression of said improved resistance to heat shock of said insert injection-molded article when subjected to 300 cycles of heating at 140° C. for 1.5 hr, and cooling to −40° C. for 1.5 hr., and a tensile strength retention after 50 hours of 85% to 92% pursuant to ISO 527 at 121° C. and 100% relative humidity after 50 hours.