| 摘要 |
The polyolefin composite film is excellent in low-temperature heat sealability, heat-sealing strength and transparency, and at least has surface layer [i]//intermediate layer [iii]//core layer[i], wherein the surface layer[i]includes a propylene resin composition including 0-50 wt % of a specific propyleneα-olefin random copolymer (A) and/or a specific 1-buteneα-olefin copolymer (E), and 50-100 wt % of a propylene polymer (B) having a melting point of 120-170° C. ((A), (E) and (B) in the surface layer totals 100 wt %); the core layer [ii]includes a propylene resin composition including 70-100 wt % of a crystalline polypropylene (C) having a melting point of 150-170° C., and 0-30 wt % of the copolymer (A) ((C) and (A) in the core layer totals 100 wt %); and the intermediate layer[iii]includes a propylene resin composition including 50-95 wt % of the crystalline polypropylene (C) and 50-5 % of the polymer (B), the copolymer (A), andor the copolymer (E) ((C), (B), (A) and (E) in the intermediate layer totals 100 wt %). |
| 主权项 |
1. A polyolefin composite film having a five-layer structure consisting of surface layer [i]/intermediate layer [iii]/core layer [ii]/intermediate layer [iii]/surface layer [i] in this order,
wherein the surface layer [i] is formed from a propylene resin composition that comprises: a propylene/1-butene copolymer (A) in an amount of 0 to 50 wt %, and a propylene/ethylene/1-butene copolymer (B) in an amount of 50 to 100 wt %, provided that the total amount of (A) and (B) in the surface layer is 100 wt %; wherein the core layer [ii] is formed from a propylene resin composition that comprises: a crystalline polypropylene (C) in an amount of 70 to 100 wt %, and the propylene/1-butene copolymer (A) in an amount of 0 to 30 wt %, provided that the total amount of (C) and (A) in the core layer is 100 wt %; and wherein the intermediate layer [iii] is formed from a propylene resin composition that comprises: the crystalline polypropylene (C) in an amount of 50 to 95 wt % and the propylene/1-butene copolymer (A) in an amount of 50 to 5 wt %, provided that the total amount of (C) and (A) in the intermediate layer is 100 wt %, wherein the propylene/1-butene copolymer (A) comprises 60 to 80 mol % of a unit derived from propylene and 20 to 40 mol % of a unit derived from 1-butene, has a melting point of 140° C. or lower or a melting that is not observed, and satisfies the following properties: (1) the intrinsic viscosity as measured in decalin at 135° C. is 0.1 to 5 dl/g, (2) the molecular weight distribution (Mw/Mn) as determined by gel permeation chromatography is 1.5 to 3, and (3) the parameter B value, which shows a randomness of copolymerized monomer chain distribution, is 0.9 to 1.5, the propylene/ethylene/1-butene copolymer (B) comprises 85 to 97 mol % of a unit derived from propylene and 3 to 15 mol % of a unit derived from ethylene and 1-butene and has a melting point of 120 to 170° C., the crystalline polypropylene (C) comprises 98 to 100 mol % of a unit derived from propylene and 0 to 2 mol % of C2-10 α-olefin excluding propylene and has a melting point of 150 to 170° C. |
