发明名称 HYDROXYL POLYACRYLATE EMULSION AND PREPARATION METHOD AND APPLICATION THEREOF
摘要 The present invention discloses a hydroxyl polyacrylate emulsion and preparation method and application thereof. The preparation method comprises: weighing an acrylate monomer and/or methacrylate monomer, a hydroxyl acrylate monomer, an acrylic acid monomer, an acrylate functional monomer and a hydroxyl oligomer, mixing uniformly to prepare a monomer mixture, and taking 10-15% of the monomer mixture to emulsify with an emulsifier, so as to prepare a seed pre-emulsion; adding the emulsifier, sodium bicarbonate and deionized water into a reactor, stirring, increasing the temperature of the reaction system, adding an initiator, stabilizing, adding all of the seed pre-emulsion drop-wise, stabilizing, adding the remaining monomer mixture and initiator drop-wise, increasing the temperature, ageing, lowering the temperature, neutralizing, remaining the temperature, and then cooling to obtain the hydroxyl polyacrylate emulsion. A coating film of an aqueous dual component polyurethane coating prepared from the hydroxyl polyacrylate emulsion and an aqueous polyisocyanate curing agent has superior hardness, luster and durability to chemicals.
申请公布号 WO2017020513(A1) 申请公布日期 2017.02.09
申请号 WO2015CN99289 申请日期 2015.12.28
申请人 SOUTH CHINA UNIVERSITY OF TECHNOLOGY;CARPOLY CHEMICAL GROUP CO., LTD. 发明人 QU, Jinqing;DUAN, Xiaojun;ZHU, Yan'an
分类号 C08F220/14;C08F2/24;C08F212/08;C08F220/06;C08F220/18;C08F220/28;C08F220/56;C09D175/04 主分类号 C08F220/14
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