发明名称 Surface-active comb copolymers
摘要 The invention relates to a copolymer whose overall structure as such and/or an optionally present segment A having at least 10 bivalent structural units in the overall structure contains surface-active bivalent structural units present in the form of long hydrocarbon chains among other forms. The copolymer is effective as a universal surface-active additive, especially also in conjunction with nonpolar media.
申请公布号 US9556299(B2) 申请公布日期 2017.01.31
申请号 US201214127811 申请日期 2012.05.04
申请人 BYK-Chemie GmbH 发明人 Nagelsdiek Renë;Göbelt Bernd;Greefrath Dorothée;Gertzen Bärbel;Omeis Jürgen
分类号 C08F8/14;C08F222/06;C08F222/08;C08F8/32;C08F299/00;C08K3/04;C08K7/24;C08L31/02;C08L35/06;C08L47/00;C08G81/02;C08F210/10;C08F36/08;C08F136/06;C08F136/08;C08F36/06;C08F236/06;C08G81/00;C08F110/10;C08F236/08;C08F10/10 主分类号 C08F8/14
代理机构 Curatolo Sidoti Co., LPA 代理人 Curatolo Sidoti Co., LPA ;Curatolo Joseph G.;Sidoti Salvatore A.
主权项 1. A copolymer whose overall structure as such, and/or an optionally present segment A of the overall structure having at least 10 bivalent structural units, contain as bivalent structural units, in each case, i) 40-90 mol % of a basic structural unit (I), ii) 10-60 mol % of a nonpolar dicarboxylic acid derivative structural unit (II), iii) 0-50 mol % of a polar dicarboxylic acid derivative structural unit (III), iv) 0-50 mol % of an oxygen group structural unit (IV), and v) 0-40 mol % of a head group structural unit (V),wherein the basic structural unit (I) is produced by reacting a monomer (Ix) containing an olefinic double bond, and does not include any species coming under said structural units (II) to (V),said nonpolar dicarboxylic acid derivative structural unit (II) is present in accordance with one or more of the formulas from the group consisting of (IIa), (IIb), (IIc), and (IId)whereinK1, K2, K3 and K4 each are the same or different, and are each represented by connectivity options in the polymer chain with the proviso, that exactly two of said connectivity options are realized per general formula,X1 and X2 are the same or different and each independently are represented by NRx and/or O wherein Rx is the same or different and is represented by H and/or a branched or unbranched C1-C12 alkyl radical,Y1 is the same or different and is represented by H, a branched or unbranched C1-C24 alkyl radical, a C6-C18 aryl radical and/or a branched or unbranched C6-C18 arylalkyl radical,R1 and R2 each are the same or different and are each independently represented by a branched or unbranched, saturated or unsaturated hydrocarbon radical having at least 50 carbon atoms,E1 is same or different and is represented by a branched or unbranched organic radical which contains at least four functional groups which are present in the form of ether groups and/or ester groups,said polar dicarboxylic acid derivative structural unit (III) is present in accordance with one or more of the formulas from the group consisting of (IIIa) and (IIIb)whereinK1, K2, K3 and K4 each are the same or different, and are each represented by connectivity options in the polymer chain with the proviso, that exactly two of said connectivity options are realized per general formula,said oxygen group structural unit (IV) does not include any species coming under dicarboxylic acid derivative structural unit (II) and is present in accordance with one or more of the formulas from the group consisting of (IVa), (IVb), (IVc), and (IVd)whereinK1, K2, K3 and K4 each are the same or different, and are each represented by connectivity options in the polymer chain with the proviso, that exactly two of said connectivity options are realized per general formula,X3 and X4 each are the same or different and each independently of one another are represented by NRy and/or O wherein Ry is the same or different and is represented by H and/or a branched or unbranched C1-C12 alkyl radical,Y2 is the same or different and is represented by H, a branched or unbranched C1-C24 alkyl radical, a C6-C18 aryl radical and/or a branched or unbranched C6-C18 arylalkyl radical,R3 is the same or different and is represented by a substituted or unsubstituted, branched or unbranched C1-C40 alkyl group, by a substituted or unsubstituted, branched or unbranched C1-C40 alkenyl group; by a substituted or unsubstituted C6-C18 aryl group, a substituted or unsubstituted, branched or unbranched C7-C18 arylalkyl group and/or a substituted or unsubstituted C4-C10 cycloalkyl group,E2 is same or different and is represented by a branched or unbranched organic radical which contains altogether at least four functional groups which are present in the form of ether groups and/or ester groups,E3 is same or different and is represented by a branched or unbranched organic radical which contains altogether at least four functional groups which are present in the form of ether groups and/or ester groups,and said head group structural unit (V) does not include any species coming under structural units (II) and (IV) and is present in accordance with one or more of the formulas from the group consisting of (Va), (Vb), (Vc), and (Vd)whereinK1, K2, K3 and K4 each are the same or different, and are each represented by connectivity options in the polymer chain with the proviso, that exactly two of said connectivity options are realized per general formula,X5 and X6 each are the same or different and each independently of one another are represented by NRz and/or O wherein Rz is the same or different and is represented by H and/or a branched or unbranched C1-C12 alkyl radical,X7 and X8 each are the same or different and each independently from one another is represented by a phosphoric acid ester group, a phosphonic acid ester group, a N,N-disubstituted amino group of the general formula (VA)and/or a quaternary ammonium group of the general formula (VB)wherein R11, R12 and R13 each are the same or different and each independently of one another are represented by a substituted or unsubstituted, branched or unbranched C1-C24-alkyl group, by a substituted or unsubstituted C4-C10 cycloalkyl group, by a substituted or unsubstituted C6-C18 aryl group and/or a substituted or unsubstituted, branched or unbranched C7-C18 arylalkyl group, wherein R11 and R12 together with each other can form a substituted or unsubstituted C4-C10 cycolalkyl group,and M− is the same or different and is represented by a carboxylate, a phosphate, a phosphate ester, a sulfate and/or a halide,R5 and R6 each are the same or different and are each independently of one another are represented by a substituted or unsubstituted, branched or unbranched C1-C24 alkylene group and/or a substituted or unsubstituted C6-C18 arylene group,R7 is the same or different and is represented by a substituted or unsubstituted, branched or unbranched C1-C40 alkyl group, by a substituted or unsubstituted, branched or unbranched C1-C40 alkenyl group; by a substituted or unsubstituted C6-C18 aryl group, a substituted or unsubstituted, branched or unbranched C7-C18 arylalkyl group and/or a substituted or unsubstituted C4-C10 cycloalkyl group.
地址 Wesel DE