| 主权项 |
1. A pesticidal composition, comprising 1-(3-pyridyl-N-oxide)pyrazole compound of formula I or any agriculturally acceptable salt thereof: wherein: (a) R1, R2, and R4 are independently selected from H, F, Cl, Br, I, substituted or unsubstituted C1-C6 alkyl, or substituted or unsubstituted C1-C6 haloalkyl, wherein each said R1, R2, and R4, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C3-C10 cycloalkyl, or C3-C10 halocycloalkyl, each of which is substituted, unsubstituted, or substituted with R11; (b) R3 is selected from H, F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C1-C6 haloalkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, OR11, C(═X1)R11, C(═X1)OR11, C(═X1)N(R11)2, N(R11)2, N(R11)C(═X1)R11, SR11, S(O)nOR11, or R11S(O)nR11, wherein each said R3, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR11, S(O)nOR11, C6-C20 aryl, or C1-C20 heterocyclyl, each of which is substituted, unsubstituted, or substituted with R11; (c) R5 is H, F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, C3-C10 cycloalkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, OR11, C(═X1)R11, C(═X1)OR11, C(═X1)N(R11)2, N(R11)2, N(R11)C(═X1)R11, SR11, S(O)nOR11, or R11S(O)nR11, wherein each said R5, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR11, S(O)nOR11, C6-C20 aryl, or C1-C20 heterocyclyl, each of which is substituted, unsubstituted, or substituted with R11; (d) R6 is H, F, Cl, Br, I, substituted or unsubstituted C1-C6 alkyl, or C1-C6 haloalkyl, wherein each said R6, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, or C3-C10 halocycloalkenyl; (e) R7 is selected from H, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C2-C6 alkynyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, C1-C6 alkyl C6-C20 aryl wherein the alkyl and aryl is independently substituted or unsubstituted, C1-C6 alkyl-(C3-C10 cyclohaloalkyl) wherein the alkyl and cyclohaloalkyl is independently substituted or unsubstituted, C1-C6 alkyl-(C3-C10 cycloalkyl) wherein the alkyl and cycloalkyl is independently substituted or unsubstituted, wherein each said R7, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR11, S(O)nOR11, C6-C20 aryl, or C1-C20 heterocyclyl, or R11aryl, each of which is substituted, unsubstituted, or substituted with R11; (f) R8 is R9S(O)nR10 or R9S(O)nH; (g) R9 is substituted or unsubstituted C2-C12 alkenyl, substituted or unsubstituted C1-C12 alkyl, or substituted or unsubstituted C3-C10 cycloalkyl, wherein each said R9, when substituted, has one or more substituents selected from F, Cl, Br, I, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C3-C10 cycloalkyl, C3-C10 halocycloalkyl, OR11, S(O)nR11, C6-C20 aryl, or C1-C20 heterocyclyl, each of which is substituted, unsubstituted, or substituted with R11; (h) R10 is selected from substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 halocycloalkyl substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C1-C20 heterocyclyl, wherein each said R10, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3 -C10 halocycloalkyl, C3-C10 halocycloalkenyl, oxo, OR11, S(O)nR11, C6-C20 aryl, or C1-C20 heterocyclyl, each of which is substituted, unsubstituted, or substituted with R11; (i) R11 is, each independently, selected from H, R8, CN, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C2-C6 alkenyloxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, substituted or unsubstituted S(O)nC1-C6 alkyl, or substituted or unsubstituted N(C1-C6 alkyl)2, wherein each said R11, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OC1-C6 alkyl, OC1-C6 haloalkyl, S(O)nC1-C6 alkyl, S(O)nOC1-C6 alkyl, C6-C20 aryl, or C1-C20 heterocyclyl; (j) Q is O, S or S(═O)n; (k) X1 is O or S; and (l) n is 0, 1 or 2. |
