发明名称 |
PREPARATION OF ALDEHYDES AND KETONES FROM ALKENES USING POLYOXOMETALATE CATALYSTS AND NITROGEN OXIDES |
摘要 |
The present invention relates to a process for preparing aldehydes and ketones by carbon-carbon bond cleavage of alkenes, wherein the process is catalysed by first row transition metal nitro coordinated polyoxometalate catalyst. The catalyst can be prepared by pre-treatment of aqua coordinated polyoxometalates with NO2, or they are formed in situ when the reactions are carried in nitroalkanes under aerobic conditions, or they are formed in situ from nitrosyl (NO) compounds in the presence of O2. |
申请公布号 |
EP3113877(A1) |
申请公布日期 |
2017.01.11 |
申请号 |
EP20150716151 |
申请日期 |
2015.03.01 |
申请人 |
Yeda Research and Development Co., Ltd. |
发明人 |
NEUMANN, Ronny;RUBINSTEIN, Amir |
分类号 |
B01J27/186 |
主分类号 |
B01J27/186 |
代理机构 |
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代理人 |
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