摘要 |
A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition. The composition, compound, device, and uses thereof according to AxMn(y-k)Mj k[Mnm(CN)(6-p-q)(NC)p(Che)r q]z. (Che)r w(Vac)(1-z).nH20 (wherein Vac is a Mn(CN)(6-p-q)(NC)p(Che))r q vacancy); wherein Che is an acid chelating agent; wherein: A= Na, K, Li; and M= Mg, Al, Ca, Sc, Ti, V, Cr, Fe, Co, Ni, Cu, Zn, Ga, Pd, Ag, Cd, In, Sn, Pb; and wherein 0 < j ≤ 4; 0 ≤ k ≤ 0.1; 0 ≤ (p+q) <6;0<x≤4;0≤y≤l;0<z≤1;0<w≤ 0.2; 0 < n ≤ 6; -3 ≤ r ≤ 3; and wherein: x + 2(y-k) +jk+(m + (r +1)q - 6)z +wr =0. |