ETHYLENE POLYMERS HAVING HIGH DENSITY

摘要

The present invention relates to an ethylene polymer comprising moieties according to Formula (IB): wherein R is a moiety comprising ≥1 and ≤10 carbon atoms; wherein R1 and R2 are each individually hydrogen or a moiety comprising ≥1 and ≤5 carbon atoms, R1 and R2 may be the same or different; wherein the ethylene polymer has a molecular weight distribution of ≥ 3.0 and ≤ 40.0; the ethylene polymer has a melting temperature of ≥ 115 °C; the ethylene polymer has a density ≥ 935 and ≤ 960 kg/m3; the ethylene polymer is essentially free from chromium, hafnium, zirconium and tetrahydrofuran; for the fraction of the ethylene polymer having a molecular weight > 100 kg/mol, the intrinsic viscosity of the ethylene polymer is related to the molecular weight according to the inequality: log I.V. < 0.65 ∗ log M - 3.10 Such polymers have high density, high purity and good processability, whilst maintaining barrier properties for oxygen and water vapour at a level similar to high-density polyethylenes produced via catalytic processes.