发明名称 PROCESS FOR THE NANOSTRUCTURING OF A BLOCK COPOLYMER FILM USING A NONSTRUCTURED BLOCK COPOLYMER BASED ON STYRENE AND ON METHYL METHACRYLATE, AND NANOSTRUCTURED BLOCK COPOLYMER FILM
摘要 The invention relates to a block copolymer film nanostructured in nanodomains at a predetermined temperature, obtained from a basic block copolymer which is nonstructured at said predetermined temperature, and at least one block of which comprises styrene and at least another block of which comprises methyl methacrylate. The block copolymer film is useful for forming nano-lithography masks.
申请公布号 US2017002127(A1) 申请公布日期 2017.01.05
申请号 US201415105245 申请日期 2014.12.15
申请人 ARKEMA FRANCE 发明人 NAVARRO Christophe;NICOLET Celia;CHEVALIER Xavier
分类号 C08F297/02;B82Y40/00;B82Y30/00;C09D153/00;G03F7/00 主分类号 C08F297/02
代理机构 代理人
主权项 1. A block copolymer film nano-structured into nano-domains at a determined temperature, obtained from a basic block copolymer non-structured at said determined temperature and having at least one block comprising styrene and at least one other block comprising methyl methacrylate, wherein the block copolymer film has the following modified chemical formula: (Aα(i)-co-Cγ)n-b-(Bβ(k)-co-Dδ)n-1-b-(Aα(i+1)-co-Eε)n-2-b-(Bβ(k+1)-co-Fζ)n-3-b- . . . -b-(Bβ(k+x)-co-Wω)n-p  (I) where: “n” represents the number of blocks of the block copolymer; “A” represents styrene and “B” represents methyl methacrylate, or conversely; “C”, “D”, “E”, “F”, . . . , “W” respectively represent a co-monomer or mixture of co-monomers incorporated in each of the blocks of the block copolymer, the co-monomer or mixture of co-monomers incorporated in a styrene block differing from the co-monomer or mixture of co-monomers incorporated in a methyl methacrylate block; the subscripts αi and βk represent the number of units of styrene or methyl methacrylate monomers contained in each block of the block copolymer, and are all independent of one another; the subscripts γ, δ, ε, ζ . . . , and ω represent the number of co-monomer units in a given block, and are all independent of one another; the subscripts αi, βk, γ, δ, ε, ζ . . . , and ω are all greater than or equal to 1.
地址 Colombes FR