发明名称 Electroluminescent polymers, process for the preparation thereof, and use thereof
摘要 The present invention relates to electroluminescent polymers which comprise indenofluorenarylamine derivatives as recurring units, to a process for the preparation thereof, to blends and formulations comprising these polymers, and to the use of these polymers or blends in electronic devices, in particular in organic light-emitting diodes, so-called OLEDs.
申请公布号 US9534077(B2) 申请公布日期 2017.01.03
申请号 US201113578439 申请日期 2011.01.18
申请人 Merck Patent GmbH 发明人 Anémian Rémi Manouk;Ludemann Aurélie;Pan Junyou
分类号 H01L51/54;C09K11/06;C08G61/12;H01L51/00;H05B33/14;H01L51/50 主分类号 H01L51/54
代理机构 Drinker Biddle & Reath LLP 代理人 Drinker Biddle & Reath LLP
主权项 1. A polymer comprising 0.01 to 100 mol % of one or more structural units of the formula (7c) or (7d),where the symbols and indices used have the following meanings: R1 is on each occurrence, identically or differently, H, F, Cl, Br, I, CN, NO2, Si(R2)3, a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 40 C atoms or a branched or cyclic alkyl, alkoxy or thioalkoxy group having 3 to 40 C atoms, each of which is optionally substituted by one or more radicals R2, where one or more non-adjacent CH2 groups is optionally replaced by —R2C═CR2—, Si(R2)2, Ge(R2)2, Sn(R2)2, C═O, C═S, C═Se, C═NR2, —O—, —S— or —CONR2— and where one or more H atoms is optionally replaced by F, Cl, Br, I, CN or NO2, or an aromatic or heteroaromatic ring system having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R2, or an aryloxy or heteroaryloxy group having 5 to 40 aromatic ring atoms, which is optionally substituted by one or more radicals R2, or a combination of these systems; two or more substituents R1 here optionally also form a mono- or polycyclic, aliphatic, aromatic or heteroaromatic ring system with one another; R2 is on each occurrence, identically or differently, H, an aliphatic hydrocarbon radical having 1 to 20 C atoms or an aromatic hydrocarbon radical having 6 to 20 C atoms; X1 is on each occurrence, identically or differently, selected from B(R1), C(R1)2, Si(R1)2, C═O, C═NR1, C═C(R1)2, O, S, S═O, SO2, N(R1), P(R1), P(═O)R1, P(═S)R1 or a combination of two, three or four of these groups; X2 is on each occurrence, identically or differently, selected from B(R1), C(R1)2, Si(R1)2, C═O, C═NR1, C═C(R1)2, O, S, S═O, SO2, N(R1), P(R1), P(═O)R1, P(═S)R1 or a combination of two, three or four of these groups; andwherein the dashed lines denote the links in the polymer and the polymer has 10 to 10,000 recurring units.
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