Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

摘要

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).;

主权项

1. A molecule having the following formulawherein:
(A) R1 is selected from the group consisting of H, F, Cl, Br, I, CN, NH2, NO2, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C3-C6)cycloalkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C3-C6)halocycloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl, (C1-C6)haloalkoxy, S(C1-C6)alkyl, S(O)(C1-C6)alkyl, S(O)2(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)haloalkyl, (C1-C6)alkyl-S(O)2NH2, and (C1-C6)haloalkyl-S(O)2NH2; (B) R2 is selected from the group consisting of H, F, Cl, Br, I, CN, NH2, NO2, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C3-C6)cycloalkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C3-C6)halocycloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl, (C1-C6)haloalkoxy, S(C1-C6)alkyl, S(O)(C1-C6)alkyl, S(O)2(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)haloalkyl, (C1-C6)alkyl-S(O)2NH2, and (C1-C6)haloalkyl-S(O)2NH2; (C) R3 is selected from the group consisting of H, F, Cl, Br, I, CN, NH2, NO2, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C3-C6)cycloalkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C3-C6)halocycloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl, (C1-C6)haloalkoxy, S(C1-C6)alkyl, S(O)(C1-C6)alkyl, S(O)2(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)haloalkyl, (C1-C6)alkyl-S(O)2NH2, and (C1-C6)haloalkyl-S(O)2NH2; (D) R4 is selected from the group consisting of H, F, Cl, Br, I, CN, NH2, NO2, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C3-C6)cycloalkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C3-C6)halocycloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl, (C1-C6)haloalkoxy, S(C1-C6)alkyl, S(O)(C1-C6)alkyl, S(O)2(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)haloalkyl, (C1-C6)alkyl-S(O)2NH2, and (C1-C6)haloalkyl-S(O)2NH2; (E) R5 is selected from the group consisting of H, F, Cl, Br, I, CN, NH2, NO2, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C3-C6)cycloalkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C3-C6)halocycloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl, (C1-C6)haloalkoxy, S(C1-C6)alkyl, S(O)(C1-C6)alkyl, S(O)2(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)haloalkyl, (C1-C6)alkyl-S(O)2NH2, and (C1-C6)haloalkyl-S(O)2NH2; (F) R6 is selected from the group consisting of H and (C1-C6)alkyl; (G) R7 is selected from the group consisting of H, F, Cl, Br, and I; (H) R8 is selected from the group consisting of F, Cl, Br, and I; (I) R9 is selected from the group consisting of H and (C1-C6)alkyl; (J) Q1 is selected from the group consisting of O and S; (K) Q2 is selected from the group consisting of O and S; (L) R10 is selected from the group consisting of H, (C1-C6)alkyl, (C2-C6)alkenyl, (C1-C6)haloalkyl, (C1-C6)alkyl(C1-C6)alkoxy, C(═O)(C1-C6)alkyl, and (C1-C6)alkoxyC(═O)(C1-C6)alkyl; (M) R11 is selected from the group consisting of H, F, Cl, Br, I, CN, NH2, NO2, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C3-C6)cycloalkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C3-C6)halocycloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl, (C1-C6)haloalkoxy, S(C1-C6)alkyl, S(O)(C1-C6)alkyl, S(O)2(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)haloalkyl, (C1-C6)alkyl-S(O)2NH2, and (C1-C6)haloalkyl-S(O)2NH2; (N) R12 is selected from the group consisting of H, F, Cl, Br, I, CN, NH2, NO2, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C3-C6)cycloalkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C3-C6)halocycloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl, (C1-C6)haloalkoxy, S(C1-C6)alkyl, S(O)(C1-C6)alkyl, S(O)2(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)haloalkyl, (C1-C6)alkyl-S(O)2NH2, and (C1-C6)haloalkyl-S(O)2NH2; (O) X1 is selected from the group consisting of
(4) N,(5) NO, and(6) CR13,wherein R13 is selected from the group consisting of H, F, Cl, Br, I, CN, NH2, NO2, CHO, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C3-C6)cycloalkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C3-C6)halocycloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl, (C1-C6)haloalkoxy, S(C1-C6)alkyl, S(O)(C1-C6)alkyl, S(O)2(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)haloalkyl, (C1-C6)alkyl-S(O)2NH2, (C1-C6)haloalkyl-S(O)2NH2, and triazolyl; (P) X2 is selected from the group consisting of
(4) N,(5) NO, and(6) CR14,wherein R14 is selected from the group consisting of H, F, Cl, Br, I, CN, NH2, NO2, (C1-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C3-C6)cycloalkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C1-C6)haloalkyl, (C3-C6)halocycloalkyl, (C2-C6)haloalkenyl, (C3-C6)halocycloalkenyl, (C1-C6)haloalkoxy, S(C1-C6)alkyl, S(O)(C1-C6)alkyl, S(O)2(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)haloalkyl, (C1-C6)alkyl-S(O)2NH2, and (C1-C6)haloalkyl-S(O)2NH2; (Q) X3 is selected from the group consisting of N(R15)(substituted or unsubstituted phenyl), N(R15)(substituted or unsubstituted heterocyclyl), and substituted or unsubstituted heterocyclyl,
(a) wherein said R15 is selected from the group consisting of H, (C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C1-C6)haloalkyl, (C1-C6)alkyl(C1-C6)alkoxy, C(═O)(C1-C6)alkyl, and (C1-C6)alkoxyC(═O)(C1-C6)alkyl,(b) wherein said substituted phenyl and substituted heterocyclyl has one or more substituents selected from the group consisting of F, Cl, Br, I, H, CN, CHO, NHOH, NO, NO2, OH, (C1-C6)alkoxy, (C1-C6)alkyl, (C1-C6)alkylphenyl, (C1-C6)alkyl-S(O)2NH2, (C1-C6)haloalkoxy, (C1-C6)haloalkyl, (C1-C6)haloalkyl-S(O)2NH2, (C2-C6)alkenyl, (C2-C6)alkynyl, (C2-C6)haloalkenyl, (C3-C6)cycloalkenyl, (C3-C6)cycloalkyl, (C3-C6)halocycloalkenyl, (C3-C6)halocycloalkyl, (C1-C6)alkyl((C1-C6)alkyl)(═NO(C1-C6)alkyl), C(═NO(C1-C6)alkyl)(C1-C6)alkyl, C(O)(C1-C6)alkyl, C(O)NH(C1-C6)alkyl, C(O)NHphenyl, C(O)O(C1-C6)alkyl, CH(═NO(C1-C6)alkyl), imidazolyl, N((C1-C6)alkyl)(C(O)(C1-C6)alkyl), N((C1-C6)alkyl)(C(O)(C1-C6)alkyl-O(C1-C6)alkyl), N((C1-C6)alkyl)(C(O)(C1-C6)haloalkyl), N((C1-C6)alkyl)(C(O)O(C1-C6)alkyl), N((C1-C6)alkyl)2, N(C(O)O(C1-C6)alkyl)2, N═CH— phenyl, NH((C1-C6)alkylC(O)(C1-C6)alkyl), NH(C(O)(C1-C6)alkyl), NH(C(O)(C2-C6)alkenyl), NH(C(O)(C3-C6)cycloalkyl), NH(C1-C6)alkyl, NH(C1-C6)alkenyl, NH(C1-C6)alkynyl, NH(C1-C6)alkylphenyl, NH(S(O)2(C1-C6)alkyl), NH2, NHC(O)(C1-C6)alkyl, NHC(O)(C1-C6)alkylphenyl, NHC(O)(C1-C6)alkylphenyl, NHC(O)(C1-C6)haloalkyl, NHC(O)(C2-C6)alkenyl, NH—C(O)O(C1-C6)alkyl, oxazolyl, phenyl, pyrazolyl, pyridinyl, S(═NCN)((C1-C6)alkyl), S(C1-C6)alkyl, S(C1-C6)haloalkyl, S(O)(═NCN)((C1-C6)alkyl), S(O)(C1-C6)alkyl, S(O)(C1-C6)haloalkyl, S(O)2(C1-C6)alkyl, S(O)2(C1-C6)haloalkyl, SCN, thiazolyl, thienyl, and triazolyl,wherein each alkoxy, alkyl, haloalkoxy, haloalkyl, alkenyl, alkynyl, haloalkenyl, cycloalkenyl, cycloalkyl, halocycloalkenyl, halocycloalkyl, imidazolyl, phenyl, pyrazolyl, pyridinyl, thiazolyl, thienyl, and triazolyl, may be optionally substituted with one or more substituents selected from the group consisting of F, Cl, Br, I, CN, OH, NH(C1-C6)alkyl, NH(C3-C6)cycloalkylCH2O(C1-C6)alkyl, NH(C3-C6)cycloalkylCH2O(C1-C6)haloalkyl, NHCH2(C3-C6)cycloalkyl, NH2, NO2, oxo, (C1-C6)alkyl, (C1-C6)alkyl, (C1-C6)alkoxy, and C(O)O—(C1-C6)alkyl; and N-oxides, agriculturally acceptable acid addition salts, salt derivatives, solvates, ester derivatives, crystal polymorphs, isotopes, resolved stereoisomers, and tautomers, of the molecules of Formula One.