发明名称 |
Process for the preparation of mixtures of di- and polyisocyanates of the diphenylmethane series with a high amount of 4,4'-methylenediphenyldiisocyanate and 2,4'-methylenediphenyldiisocyanate |
摘要 |
A fraction of diisocyanates of the diphenylmethane series is produced by reacting aniline and formaldehyde in the presence of an acid catalyst; phosgenating diamines and polyamines of diphenylmethane series containing binuclear methylenediphenyl diamine to produce a crude diisocyanate and polyisocyanate; and separating from crude diisocyanate and polyisocyanate, a fraction containing >=95 wt.% binuclear methylenediphenyl diisocyanate. Production of a fraction of diisocyanates of the diphenylmethane series containing >=95 wt.% binuclear methylenediphenyl diisocyanate by: (1) reacting aniline and formaldehyde in the presence of an acid catalyst to produce diamines and polyamines of the diphenylmethane series containing binuclear methylenediphenyl diamine; (2) phosgenating the diamines and polyamines of the diphenylmethane series containing binuclear methylenediphenyl diamine to produce a crude diisocyanate and polyisocyanate; and (3) separating from the crude diisocyanate and polyisocyanate, a fraction containing >=95 wt.% binuclear methylenediphenyl diisocyanate comprising greater than 60 wt.% 4,4'-methyl diisocyanate (MDI), 4-35 wt.% 2,4'-MDI, 0.01-10 wt.% 2,2'-MDI relative to the mass of the fraction; and not >20 ppm phenyl isocyanate in a single distillation step. Independent claims are also included for: (1) production of a diphenylmethane diisocyanate mixture comprising blending the separated fraction with a mixture containing an aromatic isocyanate; and (2) production of a polymer comprising reacting the separated fraction and/or the blend of separated fraction with a mixture containing an aromatic isocyanate with a polyol. |
申请公布号 |
EP1506957(B1) |
申请公布日期 |
2016.08.24 |
申请号 |
EP20040016412 |
申请日期 |
2004.07.13 |
申请人 |
COVESTRO DEUTSCHLAND AG |
发明人 |
PIRKL, HANS-GEORG, DR.;LIMAN, ULRICH, DR.;VIELER, ROBERT, DR.;ECHTERHOFF, RALF, DR. |
分类号 |
C07C263/10;C07C263/20;C07C265/14;C08G18/76 |
主分类号 |
C07C263/10 |
代理机构 |
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代理人 |
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主权项 |
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