发明名称 CONVERSION OF ALKANES TO ORGANOSELENIUMS AND ORGANOTELLURIUMS
摘要 The invention provides processes and materials for the efficient and costeffective functionalization of alkanes and heteroalkanes, comprising contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium, which can be carried out at a temperature of less than 300 C. Isolation of the alkylselenium or alkyltellurium intermediate allows the subsequent conversion to products not necessarily compatible with the initial reaction conditions, such as amines, stannanes, organosulfur compounds, acyls, halocarbons, and olefins.
申请公布号 EP3030635(A4) 申请公布日期 2016.07.27
申请号 EP20140833997 申请日期 2014.08.06
申请人 THE SCRIPPS RESEARCH INSTITUTE;PERIANA, ROY A.;KONNICK, MICHAEL M.;HASHIGUCHI, BRIAN G. 发明人 PERIANA, ROY A.;KONNICK, MICHAEL M.;HASHIGUCHI, BRIAN G.
分类号 C07C391/00;C07C1/32;C07C11/02;C07C17/093;C07C319/02;C07C319/14;C07C321/04;C07C321/14;C07C395/00 主分类号 C07C391/00
代理机构 代理人
主权项
地址