GROUP III NITRIDE CRYSTALS, THEIR FABRICATION METHOD, AND METHOD OF FABRICATING BULK GROUP III NITRIDE CRYSTALS IN SUPERCRITICAL AMMONIA

摘要

In one instance, the invention provides a group III nitride crystal having a first side exposing nitrogen polar c-plane of single crystalline or highly oriented polycrystalline group III nitride and a second side exposing group III polar surface, polycrystalline phase, or amorphous phase of group III nitride. Such structure is useful as a seed crystal for ammonothermal growth of bulk group III nitride crystals. The invention also discloses the method of fabricating such crystal. The invention also discloses the method of fabricating a bulk crystal of group III nitride by ammonothermal method using such crystal.

主权项

1. A method of fabricating a bulk crystal of gallium nitride in a high-pressure reactor comprising
(a) placing at least one gallium nitride seed crystal in the high pressure reactor; (b) placing at least one kind of mineralizer in the high pressure reactor; (c) placing at least one flow-restricting plate in the high pressure reactor (d) placing gallium containing nutrient in the high pressure reactor; (e) placing ammonia in the high pressure reactor; (f) sealing the high pressure reactor; (g) heating the high pressure reactor with appropriate temperature difference between the region for the seed crystals and the region for the nutrient;wherein the crystal structural quality of the nitrogen polar surface of the gallium nitride seed crystal is better than the crystal structural quality of the gallium polar surface of the seed crystal.