| 摘要 |
The present invention relates to: a bio-based polycarbonate ester comprising: (i) repeat unit 1 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and carbonate; and (ii) repeat unit 2 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and 1,4-cyclohexanedicarboxylate; and a preparation method for the bio-based polycarbonate ester, comprising the steps of: (1) preparing a compound represented by formula 3 through a trans-esterification or esterification reaction of a compound represented by formula 2 and phenol; and (2) preparing a compound comprising a repeat unit represented by formula 1 through a polycarbonate melt polycondensation reaction of the compound represented by formula 3 prepared in step (1), a compound represented by formula 4, and 1,4:3,6-dianhydrohexitol. The bio-based polycarbonate ester, according to the present invention, is capable of controlling advantages and disadvantages of physical properties obtained from each repeat unit, and has high thermal resistance and high transparency, and thus is capable of being effectively used for various uses. |
