Melt molding method of germanium

摘要

In a melt molding method of germanium, the germanium which is brought into a molten state is sealed in molding dies in an inert gas atmosphere. The molding dies are temperature-controlled from the outside. While gradually cooling the molding dies at a portion or a plurality of portions thereof up to the whole, the germanium is gradually solidified from a side of the portion or sides of the plurality of portions up to the whole. An external ambient temperature of the molding dies is controlled to decrease gradually while ensuring a temperature below a germanium melting point temperature but higher than an inner temperature of the molding die which is cooled. After solidification of the germanium is completed, cooling of the molding dies is continued, and the external ambient temperature is decreased to mold the germanium.

主权项

1. A melt molding method of germanium, including the steps of:
arranging a molding die including an upper die and a lower die in an inert gas atmosphere, the upper die raised to be separated from the lower die; arranging a heating device around the upper and lower dies so as to provide a space between the heating device and the upper and lower dies; placing a solid germanium raw material in the lower die; heating the molding die with the heating device while keeping the upper and lower dies separated, so that the germanium raw material is melted; turning down a set temperature of the heating device after both the upper and lower dies reach a temperature higher than a melting point of the germanium raw material, the temperature of each of the upper and lower dies being measured at a point in the upper and lower dies close to a die surface of the upper and lower dies; lowering the upper die to abut the lower die; cooling the molding die by blowing cooling inert gas to a central portion of the upper die from above and to a central portion of the lower die from below so that each one of the upper and lower dies is gradually cooled outward from the central portion thereof and the germanium is solidified; and further lowering the set temperature of the heating device after the solidification of the germanium raw material is completed; wherein:
the solidification of the germanium raw material is complete when the temperatures of the upper and lower dies decrease subsequent to the blowing of the cooling inert gas, the temperatures of the upper and lower dies thereafter increase due to latent heat of the germanium raw material, and the temperatures of the upper and lower dies begin to decrease again; andthe cooling of the molding die includes controlling the set temperature of the heating device so that an external ambient temperature in the space between the molding die and the heating device decreases while being kept at a temperature equal to or higher than the temperatures of the upper and lower dies until the solidification of the germanium raw material is complete.