发明名称 MULTI-FUNCTIONAL PHENOLIC RESINS
摘要 Disclosed herein are compositions and methods of making phenolic compounds and phenolic resins. The resins include multifunctional epoxies, amino glycidyl derivatives, alkanoate derivatives, alkyl ether derivatives, and multi-functional amines prepared from hydroxymethyl derivatives of novolac resin.
申请公布号 US2016137570(A1) 申请公布日期 2016.05.19
申请号 US201314898420 申请日期 2013.06.13
申请人 EMPIRE TECHNOLOGY DEVELOPMENT LLC 发明人 ADAM Georgius Abidal
分类号 C07C39/15;C07C69/54;C07C265/08;C07C233/20;C07D303/30;C07C43/178;C07D303/36;C07C37/20;C07C213/02;C07C67/00;C07C263/10;C07C231/02;C07D301/28;C07C41/01;C07C215/50 主分类号 C07C39/15
代理机构 代理人
主权项 1. A compound of formula I: wherein: a is an integer from 1 to 10; R1 is H, Z, —C(═O)—CH═CH2, —(CH2—CH2—O)nH, —(CH2—CH2—CH2—O)nH, or —(CH2—CH2—O)n—(CH2—CH(CH3)—O)nH, where each n is, independently, an integer from 1 to 18; each R2 is, independently, H, Z, —C(═O)—CH═CH2, —(CH2—CH2—O)pH, —(CH2—CH2—CH2—O)pH, or —(CH2—CH2—O)p—(CH2—CH(CH3)—O)pH, where each p is, independently, an integer from 1 to 18; R3 is H, Z, —C(═O)—CH═CH2, —(CH2—CH2—O)qH, —(CH2—CH2—CH2—O)qH, or —(CH2—CH2—O)q—(CH2—CH(CH3)—O)qH, where each q is, independently, an integer from 1 to 18; R4 is —OH, —NH2, —O—Z, —N(Z)2, —N(CH2—O—Z)2, —N(CH2OH)2, —N(CH2CH2—O—Z)2, —N(CH2NH2)2, —N(CH2CH2OH)2, —CH2—O—Z, —CH2—OH, —CH2—NH2, —N(CH3)2, —O-(alkylene)-CH3, —CH2—Y, —NCO, —O—C(═O)—(CH2)r—CH3, —NH—Z, —N[CH2O—C(═O)—CH═CH2]2, —NH—C(═O)CH═CH2, —CH2CH2—O—Z, —CH2CH2OH, —O—C(═O)—CH═CH2, —N(CH2—CH2—NH2)2, —(CH2—CH2—O)rH, —(CH2—CH2—CH2—O)rH, —N[CH2—CH2—O—C(═O)—CH═CH2]2, or —N[CH2—CH2—NH—C(═O)—CH═CH2]2, where r is an integer from 1 to 18; R5 is —OH, —NH2, —O—Z, —N(Z)2, —N(CH2—O—Z)2, —N(CH2OH)2, —N(CH2CH2—O—Z)2, —N(CH2NH2)2, —N(CH2CH2OH)2, —CH2—O—Z, —CH2—OH, —CH2—NH2, —N(CH3)2, —O-(alkylene)-CH3, —CH2—Y, —NCO, —O—C(═O)—(CH2)rCH3, —NH—Z, —N[CH2O—C(═O)—CH═CH2]2, —NH—C(═O)CH═CH2, —CH2CH2—O—Z, —CH2CH2OH, —O—C(═O)—CH═CH2, —N(CH2—CH2—NH2)2, —(CH2—CH2—O)tH, —(CH2—CH2—CH2—O)tH, —N[CH2—CH2—O—C(═O)—CH═CH2]2, or —N[CH2—CH2—NH—C(═O)—CH═CH2]2, where t is an integer from 1 to 18; R6 is —OH, —NH2, —O—Z, —N(Z)2, —N(CH2—O—Z)2, —N(CH2OH)2, —N(CH2CH2—O—Z)2, —N(CH2NH2)2, —N(CH2CH2OH)2, —CH2—O—Z, —CH2—OH, —CH2—NH2, —N(CH3)2, —O-(alkylene)-CH3, —CH2—Y, —NCO, —O—C(═O)—(CH2)v—CH3, —NH—Z, —N[CH2O—C(═O)—CH═CH2]2, —NH—C(═O)CH═CH2, —CH2CH2—O—Z, —CH2CH2OH, —O—C(═O)—CH═CH2, —N(CH2—CH2—NH2)2, —(CH2—CH2—O)vH, —(CH2—CH2—CH2—O)vH, —N[CH2—CH2—O—C(═O)—CH═CH2]2, or —N[CH2—CH2—NH—C(═O)—CH═CH2]2, where v is an integer from 1 to 18; each R7 is, independently, —OH, —NH2, —O—Z, —N(Z)2, —N(CH2—O—Z)2, —N(CH2OH)2, —N(CH2CH2—O—Z)2, —N(CH2NH2)2, —N(CH2CH2OH)2, —CH2—O—Z, CH2—NH2, —N(CH3)2, —O-(alkylene)-CH3, —CH2—Y, —NCO, —O—C(═O)—(CH2)w—CH3, —NH—Z, —N[CH2O—C(═O)—CH═CH2]2, —NH—C(═O)CH═CH2, —CH2CH2—O—Z, —CH2CH2OH, —O—C(═O)—CH═CH2, —N(CH2—CH2—NH2)2, —(CH2—CH2—O)wH, —(CH2—CH2—CH2—O)wH, —N[CH2—CH2—O—C(═O)—CH═CH2]2, or —N[CH2—CH2—NH—C(═O)—CH═CH2]2, where w is an integer from 1 to 18; R8 is —OH, —NH2, —O—Z, —N(Z)2, —N(CH2—O—Z)2, —N(CH2OH)2, —N(CH2CH2—O—Z)2, —N(CH2NH2)2, —N(CH2CH2OH)2, —CH2—O—Z, —CH2—OH, —CH2—NH2, —N(CH3)2, —O-(alkylene)-CH3, —CH2—Y, —NCO, —O—C(═O)—(CH2)x—CH3, —NH—Z, —N[CH2O—C(═O)—CH═CH2]2, —NH—C(═O)CH═CH2, —CH2CH2—O—Z, —CH2CH2OH, —O—C(═O)—CH═CH2, —N(CH2—CH2—NH2)2, —(CH2—CH2—O)xH, —(CH2—CH2—CH2—O)xH, —N[CH2—CH2—O—C(═O)—CH═CH2]2, or —N[CH2—CH2—NH—C(═O)—CH═CH2]2, where x is an integer from 1 to 18; Z isand Y is Cl, Br, F, or I.
地址 Wilmington DE US