Membrane electrode assembly, fuel cell comprising the membrane electrode assembly, and method for preparing an electrode catalyst

摘要

Disclosed is an electrode catalyst comprising: (a) a support with a specific surface area of at least 1200 m2/g; and (b) platinum or platinum-containing alloy particles on the support, wherein the platinum is supported on the electrode catalyst in an amount of 56˜90 wt % based on the total weight of the electrode catalyst. A membrane electrode assembly (MEA) comprising the electrode catalyst and a fuel cell using the MEA are also disclosed. The electrode catalyst comprises platinum or platinum-containing alloy particles highly dispersed on a support with a large surface area in an amount of 56 wt % or more, and thus has an extended catalytically active region, resulting in improvement in the quality of a fuel cell.

主权项

1. A method for preparing an electrode catalyst comprising 56-90 wt % of platinum supported thereon, which comprises the steps of:
(a) dispersing a support into a solvent to form a support dispersion, and adding a first pH modifier thereto to provide an alkalified support dispersion; (b) adding a solution of a platinum precursor or platinum-containing alloy precursor compound and a second pH modifier to the alkalified support dispersion, and further adding a reducing agent thereto to perform reaction of the alkalified support dispersion to produce a platinum-containing dispersion; and (c) filtering the platinum-containing dispersion after step (b) to obtain a powder, and drying the powder, wherein pH of the alkalified support dispersion after the addition of the second pH modifier is 8-11, and wherein the solution is added portionwise in step (b) to the alkalified support dispersion, and an amount of each portion of the solution is 1/N of the total amount of the solution, where 1