Phosphor and light-emitting device

摘要

A phosphor has the general formula (M2x,M3y,M4z)mM1O3X(2/n), wherein M1 represents at least one element including at least Si and selected from the group consisting of Si, Ge, Ti, Zr, and Sn, M2 represents at least one element including at least Ca and selected from the group consisting of Ca, Mg, Cd, Co, and Zn, M3 represents at least one element including at least Sr and selected from the group consisting of Sr, Ra, Ba, and Pb, X represents at least one halogen element, M4 represents at least one element including at least Eu2+ and selected from the group consisting of rare-earth elements and Mn, m is in the range 1≦m≦4/3, n is in the range 5≦n≦7, and x, y, and z are each in such a range as to satisfy x+y+z=1, 0.45≦x≦0.8, 0.05≦y≦0.45, and 0.45, and 0.03≦z≦0.35.

主权项

1. A light-emitting device, comprising:
a light-emitting element which emits ultraviolet light or short-wavelength visible light; a first phosphor which is excited by the ultraviolet light or the short-wavelength visible light to emit visible light; and a second phosphor which is excited by the ultraviolet light or the short-wavelength visible light to emit visible light of a color different from that of the visible light emitted from the first phosphor, the light-emitting device being configured to produce a mixed color by mixing light beams from the respective phosphors and configured to emit light with a color temperature of 3,200 K or less, wherein the first phosphor has the general formula (M2x,M3y,M4z)mM1O3X(2/n), wherein M1 represents at least one element including at least Si and selected from the group consisting of Si, Ge, Ti, Zr, and Sn, M2 represents at least one element including at least Ca and selected from the group consisting of Ca, Mg, Cd, Co, and Zn, M3 represents at least one element including at least Sr and selected from the group consisting of Sr, Ra, Ba, and Pb, X represents at least one halogen element, M4 represents at least one element including at least Eu2+ and selected from the group consisting of rare-earth elements and Mn, m is in the range 1≦m≦4/3, n is in the range 5≦n≦7, and x, y, and z are each in such a range as to satisfy x+y+z=1, 0.45≦x≦0.8, 0.05≦y≦0.45, and 0.03≦z≦0.35.