发明名称 Herbicidally and insecticidally active thiazolopyridinones
摘要 Thiazolopyridinones of the general formula (I) are described as herbicides.; In this formula (I), R1, R2, R3 and R4 represent radicals such as hydrogen, organic radicals such as alkyl and other radicals such as halogen, nitro and cyano.
申请公布号 US9307767(B2) 申请公布日期 2016.04.12
申请号 US201314386155 申请日期 2013.03.25
申请人 BAYER INTELLECTUAL PROPERTY GMBH 发明人 Waldraff Christian;Lehr Stefan;Angermann Alfred;Dietrich Hansjoerg;Dittgen Jan;Gatzweiler Elmar;Rosinger Christopher Hugh;Becker Angela
分类号 A01N43/90;C07D513/04 主分类号 A01N43/90
代理机构 MMWV IP, LLC 代理人 MMWV IP, LLC
主权项 1. A thiazolopyridinone of formula (I) and/or a salt thereof in which R1 represents hydrogen, halogen, nitro, cyano, (C1-C6)-alkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, (C1-C6)-alkoxy, (C1-C6)-alkylthio, (C1-C6)-alkylsulfinyl, (C1-C6)-alkylsulfonyl, (C3-C6)-cycloalkyl, (C1-C6)-alkoxy-(C1-C6)-alkyl, di-(C1-C6)-alkoxy-(C1-C6)-alkyl or (C1-C6)-alkylthio-(C1-C6)-alkyl, each of which is substituted by n halogen atoms, R2 represents hydrogen, (C1-C6)-alkyl, (C2-C6)-alkenyl, (C3-C6)-alkynyl, (C3-C6)-cycloalkyl, (C1-C6)-alkoxy-(C1-C6)-alkyl or di-(C1-C6)-alkoxy-(C1-C6)-alkyl, (C1-C6)-alkylthio-(C1-C6)-alkyl, (C1-C6)-alkylsulfinyl-(C1-C6)-alkyl, (C1-C6)-alkylsulfonyl-(C1-C6)-alkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, cyano-(C1-C6)-alkyl, each of which is substituted by n halogen atoms, or phenyl or benzyl, each of which is substituted by n radicals from the group consisting of halogen, (C1-C6)-alkyl and (C1-C6)-alkoxy, R3 represents hydroxy, O—C(═O)R7, O—C(=L)MR8, O—SO2R9, O—P(=L)R10R11, O—C(=L)NR12R13, O-E or O—R14, R4 represents R4a or R4b, R4a represents aryl which is substituted by n radicals R5 and one radical R6, R4b represents 2-furyl, 3-furyl, 2-thienyl, 3-thienyl, 1-pyrrolyl, 2-pyrrolyl, 3-pyrrolyl, 3-isoxazolyl, 4-isoxazolyl, 5-isoxazolyl, 3-isothiazolyl, 4-isothiazolyl, 5-isothiazolyl, 1-pyrazolyl, 3-pyrazolyl, 4-pyrazolyl, 5-pyrazolyl, 2-oxazolyl, 4-oxazolyl, 5-oxazolyl, 2-thiazolyl, 4-thiazolyl, 5-thiazolyl, 1-imidazolyl, 2-imidazolyl, 4-imidazolyl, 5-imidazolyl, 1,2,4-oxadiazol-3-yl, 1,2,4-oxadiazol-5-yl, 1,2,4-thiadiazol-3-yl, 1,2,4-thiadiazol-5-yl, 1,3,4-oxadiazol-2-yl, 1,3,4-thiadiazol-2-yl, 1,2,4-triazol-1-yl, 1,2,4-triazol-3-yl, 1,2,4-triazol-4-yl, 1,2,4-triazol-5-yl, 1,2,3-triazol-1-yl, 1,2,3-triazol-2-yl, 1,2,3-triazol-4-yl, tetrazol-1-yl, tetrazol-2-yl, tetrazol-5-yl, indol-1-yl, indol-2-yl, indol-3-yl, isoindol-1-yl, isoindol-2-yl, benzofur-2-yl, benzothiophen-2-yl, benzofur-3-yl, benzothiophen-3-yl, benzoxazol-2-yl, benzothiazol-2-yl, benzimidazol-2-yl, indazol-1-yl, indazol-2-yl, indazol-3-yl, 2-pyridinyl, 3-pyridinyl, 4-pyridinyl, 3-pyridazinyl, 4-pyridazinyl, 2-pyrimidinyl, 4-pyrimidinyl, 5-pyrimidinyl, 2-pyrazinyl, 1,3,5-triazin-2-yl, 1,2,4-triazin-3-yl, 1,2,4-triazin-5-yl or 1,2,4-triazin-6-yl, substituted by n radicals R5 and by m radicals R6, R5 represents hydrogen, halogen, nitro, cyano, (C1-C6)-alkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, (C1-C6)-alkoxy, (C1-C6)-alkylthio, (C1-C6)-alkylsulfinyl, (C1-C6)-alkylsulfonyl, (C3-C6)-cycloalkyl, (C1-C6)-alkoxy-(C1-C6)-alkyl or (C1-C6)-alkylthio-(C1-C6)-alkyl, each of which is substituted by n halogen atoms, R6 represents aryl or heteroaryl, each of which is substituted by s radicals R5, E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulfur, M represents oxygen or sulfur, R7 represents (C1-C6)-alkyl, (C2-C6)-alkenyl, (C1-C6)-alkoxy-(C1-C6)-alkyl, di-(C1-C6)-alkoxy-(C1-C6)-alkyl or (C1-C6)-alkylthio-(C1-C6)-alkyl, each of which is substituted by n halogen atoms, a fully saturated 3- to 6-membered ring consisting of 3 to 5 carbon atoms and 1 to 3 heteroatoms from the group consisting of oxygen, sulfur and nitrogen, which ring is substituted by n radicals from the group consisting of halogen, (C1-C6)-alkyl and (C1-C6)-alkoxy, or (C3-C6)-cycloalkyl, phenyl, phenyl-(C1-C6)-alkyl, phenoxy-(C1-C6)-alkyl or heteroaryloxy-(C1-C6)-alkyl, each of which is substituted by n radicals from the group consisting of halogen, (C1-C6)-alkyl and (C1-C6)-alkoxy, R8 represents (C1-C6)-alkyl, (C2-C6)-alkenyl, (C1-C6)-alkoxy-(C1-C6)-alkyl or di-(C1-C6)-alkoxy-(C1-C6)-alkyl, each of which is substituted by n halogen atoms, or (C3-C6)-cycloalkyl, phenyl or benzyl, each of which is substituted by n radicals from the group consisting of halogen, (C1-C6)-alkyl and (C1-C6)-alkoxy, R9, R10, R11 independently of one another represent (C1-C6)-alkyl, (C1-C6)-alkoxy, N—(C1-C6)-alkylamino, N,N-di-(C1-C6)-alkylamino, (C1-C6)-alkylthio, (C2-C6)-alkenyl or (C3-C6)-cycloalkylthio, each of which is substituted by n halogen atoms, or phenyl, benzyl, phenoxy or phenylthio, each of which is substituted by n radicals from the group consisting of halogen, (C1-C6)-alkyl and (C1-C6)-alkoxy, R12, R13 independently of one another each represent hydrogen, (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C2-C6)-alkenyl, (C1-C6)-alkoxy or (C1-C6)-alkoxy-(C1-C6)-alkyl, substituted by n halogen atoms, phenyl or benzyl, each of which is substituted by n radicals from the group consisting of halogen, (C1-C6)-alkyl and (C1-C6)-alkoxy, or R12 and R13 together with the nitrogen atom to which they are attached form a 3- to 6-membered ring containing 2 to 5 carbon atoms and in each case 0 or 1 oxygen or sulfur atoms, R14 represents (C1-C6)-alkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, (C1-C6)-alkoxy-(C1-C6)-alkyl, (C1-C6)-alkylthio-(C1-C6)-alkyl or di-(C1-C6)-alkoxy-(C1-C6)-alkyl, each of which is substituted by n halogen atoms, (C3-C6)-cycloalkyl substituted by n radicals from the group consisting of halogen, (C1-C6)-alkyl and (C1-C6)-alkoxy, a fully saturated 3- to 6-membered ring consisting of 3 to 5 carbon atoms and 1 to 3 heteroatoms from the group consisting of oxygen, sulfur and nitrogen, which ring is substituted by n radicals from the group consisting of halogen, (C1-C6)-alkyl and (C1-C6)-alkoxy, phenyl, phenyl-(C1-C6)-alkyl, heteroaryl, phenoxy-(C1-C6)-alkyl or heteroaryloxy-(C1-C6)-alkyl, substituted by n radicals from the group consisting of halogen, (C1-C6)-alkyl and (C1-C6)-alkoxy, m represents 0 or 1, n represents 0, 1, 2 or 3, s represents 0, 1, 2, 3 or 4.
地址 Monheim am Rhein DE