发明名称 |
Solid electrolyte material, lithium battery, and method of producing solid electrolyte material |
摘要 |
A main object of the present invention is to provide a Li—La—Ti—O based solid electrolyte material having high Li ion conductivity in the crystal grain boundary. The present invention attains the object by providing solid electrolyte material represented by a general formula: Li3x(La(2/3−x)−aM1a) (Ti1−bM2b)O3, wherein “x” is 0<x<0.17; “a” is 0≦a≦0.5; “b” is 0≦b≦0.5; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga, and wherein the solid electrolyte material is a crystalline material, is in thin film form, and has a thickness of 250 nm to 850 nm. |
申请公布号 |
US9300008(B2) |
申请公布日期 |
2016.03.29 |
申请号 |
US201013512649 |
申请日期 |
2010.04.13 |
申请人 |
TOYOTA JIDOSHA KABUSHIKI KAISHA |
发明人 |
Yada Chihiro;Yokoishi Shoji;Hayden Brian Elliott;Le Gall Thierry;Smith Duncan Clifford Alan;Lee Christopher Edward |
分类号 |
H01M10/0562;H01M10/052;H01B1/12;H01M4/485;H01M4/505;H01M4/525 |
主分类号 |
H01M10/0562 |
代理机构 |
Oblon, McClelland, Maier & Neustadt, L.L.P. |
代理人 |
Oblon, McClelland, Maier & Neustadt, L.L.P. |
主权项 |
1. A solid electrolyte thin film of formula (I):
Li3x(La(2/3−x)−aM1a)(Ti1−bM2b)O3 (I),wherein:
x is 0<x<0.17; a is 0≦a≦0.5; b is 0≦b≦0.5; M1 is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and M2 is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga, wherein the solid electrolyte thin film consists of a crystalline material, and has a thickness of 250 nm to 850 nm. |
地址 |
Toyota-shi JP |