POLYCRYSTALLINE CHALCOGENIDE CERAMIC MATERIAL

摘要

The invention relates to a polycrystalline IR transparent material produced by sintering chalcogenide powder, e.g., ZnS powder, using hot uniaxial pressing followed by hot isostatic pressing. The microstructure of the material described in this disclosure is much finer than that found in material produced using the state of the art process. By using a powder with a particle size fine enough to improve sintering behavior but coarse enough to prevent a lowering of the wurtzite-sphalerite transition temperature, a highly transparent material with improved strength is created without degrading the optical properties. A high degree of transparency is achieved during hot pressing by applying pressure after the part has reached a desired temperature. This allows some degree of plastic deformation and prevents rapid grain growth which can entrap porosity. The crystallographic twins created during this process further inhibit grain growth during hot isostatic pressing.

主权项

1. A process according to claim 16, wherein the polycrystalline chalcogenide ceramic material prepared by said process is a ceramic body comprising a chalcogenide material in a polymorphic form having a cubic structure and having an extinction coefficient of ≦2.75 cm−1 at 1100 nm and a Vickers hardness of ≧180 kg/mm2.