发明名称 Molecular near-infrared to visible light upconversion luminescence
摘要 The present invention relates to a self-assembled helical metallic complex of formula (1): [M1M2M3(L1)3] (1) said metallic complex forming a triad donor (M1)/acceptor (M2)/donor (M3), wherein the efficiency of the intermolecular energy transfer between the pair of donors (M/) and (M3) to the acceptor (M2) is from 30% to 70% and the L1 ligand-field strength of the donors (M1) and (M3) is at least 19000 cm−1.
申请公布号 US9291561(B2) 申请公布日期 2016.03.22
申请号 US201213980231 申请日期 2012.02.14
申请人 SICPA HOLDING SA 发明人 Hauser Andreas;Piguet Claude
分类号 C07F11/00;B41M3/14;G01N21/64 主分类号 C07F11/00
代理机构 Greenblum & Bernstein, P.L.C. 代理人 Greenblum & Bernstein, P.L.C.
主权项 1. A security element comprising a helical metallic complex as a security feature material, the helical metallic complex comprising at least three metal atoms, M1, M2 and M3, two of said metal atoms M1 and M3 are selected from Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Lu, Hf, Ta, W, Re, Os, Ir, Pt, La, Ce, Pr, Nd, Pm, Sm Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, metal M1 and M3 being the same metal atoms, and at least one metal atom M2 being selected from Tm, Er, Yb, wherein said complex comprises at least two benzimidazole molecules, so as to form a complex with said metal atoms, wherein each of said benzimidazole molecules is bound to at least two metal atoms, wherein said benzimidazole molecules assume a helical conformation and said metals are bound in the center of the helical conformation, wherein the metal M2 is situated between metals M1 and M3; and the metallic complex absorbs light in the spectrum of infrared and emits light in the visible spectrum.
地址 Prilly CH