发明名称 |
RECOVERY METHOD AND REUSE METHOD OF OXO ACID CATALYST |
摘要 |
Provided is a method for easily and efficiently recovering an oxoacid catalyst without deterioration in reaction product yield and catalytic activity, where the oxoacid catalyst has been used in a reaction for oxidizing an organic compound with hydrogen peroxide, also provided is a method for producing an oxide in which an organic compound is oxidized with hydrogen peroxide using the oxoacid catalyst recovered by the method, to yield the corresponding oxide.;A method according to the present invention recovers an oxoacid catalyst used in a reaction for oxidizing an organic compound with hydrogen peroxide in an aqueous/organic solvent two-phase system. The method includes Step 1 in which the pH in the reaction system is adjusted to 5.0 or higher so as to transfer the oxoacid catalyst to the aqueous phase, and the organic phase is removed. |
申请公布号 |
US2016074856(A1) |
申请公布日期 |
2016.03.17 |
申请号 |
US201414786251 |
申请日期 |
2014.04.17 |
申请人 |
DAICEL CORPORATION |
发明人 |
KITAYAMA Kenji;SHIBATA Hikaru;SUZUKI Takamasa;UEHARA Kazuhiro |
分类号 |
B01J38/64;C07D303/02;B01J23/30 |
主分类号 |
B01J38/64 |
代理机构 |
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代理人 |
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主权项 |
1. A method for recovering an oxoacid catalyst, the oxoacid catalyst having been used in a reaction for oxidizing an organic compound with hydrogen peroxide in an aqueous/organic solvent two-phase reaction system, the method comprising
Step 1 of adjusting a pH in the reaction system to 5.0 or higher so as to transfer the oxoacid catalyst to the aqueous phase, and removing the organic phase. |
地址 |
Osaka-shi, Osaka JP |