| 发明名称 | Method for purifying lithium bicarbonate | ||
| 摘要 | The invention relates to a method for purifying impure lithium bicarbonate by means of a cation exchange resin. In addition to solution purification by ion exchange, the treatment stages include the regeneration of impurity metals bound to the resin. Regeneration consists of washing the resin with water, elution with acid solution, washing with water, neutralization with alkali solution and washing with water. It is characteristic of the method that neutralization is performed with sodium hydroxide solution. | ||
| 申请公布号 | US9284626(B2) | 申请公布日期 | 2016.03.15 |
| 申请号 | US201013255099 | 申请日期 | 2010.03.01 |
| 申请人 | Outotec Oyj | 发明人 | Tiihonen Marika |
| 分类号 | C01D15/08;C22B26/12;B01J39/04;B01J49/00;C22B3/20;C22B3/42 | 主分类号 | C01D15/08 |
| 代理机构 | Chernoff, Vilhauer, McClung & Stenzel, LLP | 代理人 | Chernoff, Vilhauer, McClung & Stenzel, LLP |
| 主权项 | 1. A method for purifying an impure aqueous solution of lithium bicarbonate containing divalent metal cations the method comprising the steps of: a) providing a bed of an organic weak acid cation exchange resin that is substantially free of multivalent cations and has been neutralized with sodium ions, wherein the resin has a selectivity for cations in the sequence of Li+<Na+<multivalent metal cations<H+; b) passing the impure aqueous solution of lithium bicarbonate through the bed provided by step a) to remove the divalent metal cations from the impure aqueous solution; c) collecting a solution containing sodium ions from the bed at a beginning of step b); d) collecting a purified aqueous solution of lithium bicarbonate from the bed during step b) and following step c); e) passing the solution collected in step c) through the bed to displace lithium ions from the bed to produce a solution containing lithium ions following step d); f) collecting the solution containing lithium ions during step e); g) passing water through the bed following step e) to rinse the bed; h) passing an aqueous solution containing an acid through the bed following step g) to elute the divalent metal cations from the cation exchange resin; i) passing water through the bed following step h) to rinse the bed; j) passing an aqueous solution containing sodium hydroxide through the bed following step i) to neutralize the cation exchange resin thereby providing the bed recited in step a). | ||
| 地址 | Espoo FI | ||