发明名称 METHOD FOR MAKING METHYL METHACRYLATE FROM PROPIONALDEHYDE AND FORMALDEHYDE VIA OXIDATIVE ESTERIFICATION
摘要 A process for forming methyl methacrylate can comprise: reacting ethylene, carbon monoxide, and hydrogen, in the presence of a first catalyst comprising a metal carbonyl; removing a first reaction product comprising propionaldehyde; reacting the first reaction product with formaldehyde; removing a second reaction product comprising methacrolein; reacting the second reaction product with oxygen and methanol in the presence of a second catalyst to form a third reaction product comprising methyl methacrylate. Another process for forming methyl methacrylate can comprising: reacting ethylene with carbon monoxide to form propionaldehyde; reacting the propionaldehyde with formaldehyde to form methacrolein; and reacting the methacrolein with methanol and oxygen to form the methyl methacrylate.
申请公布号 US2016068465(A1) 申请公布日期 2016.03.10
申请号 US201514945007 申请日期 2015.11.18
申请人 Saudi Basic Industries Corporation 发明人 Allman James Malcolm;Kauffman James
分类号 C07C67/44;C07C45/75;C07C45/50 主分类号 C07C67/44
代理机构 代理人
主权项 1. A process for forming methyl methacrylate, comprising: reacting ethylene, carbon monoxide, and hydrogen, in the presence of a first catalyst comprising a metal carbonyl; removing a first reaction product comprising propionaldehyde; reacting the first reaction product with formaldehyde; removing a second reaction product comprising methacrolein; and reacting the second reaction product with oxygen and methanol in the presence of a second catalyst to form a third reaction product comprising methyl methacrylate.
地址 Riyadh SA