Air separation method and apparatus

摘要

A cryogenic air separation method and apparatus in which first and second liquid streams are produced. The first liquid stream has a higher oxygen content than air and can consist of a higher pressure distillation column bottoms and the second liquid stream, for instance, air, has a lower oxygen content than the first liquid stream and an argon content no less than the air. The second liquid stream is subcooled through indirect heat exchange with the first liquid stream and both of such streams are introduced into the lower pressure column. The second liquid stream is introduced into the lower pressure column above that point at which the crude liquid oxygen column bottoms or any portion thereof is introduced into the lower pressure column to increase a liquid to vapor ratio below the introduction of the second liquid stream and therefore, reduce the oxygen present within the column overhead.

主权项

1. An air separation method comprising:
conducting a cryogenic rectification process that comprises distilling compressed and purified air, formed by compressing the air and then purifying the air within a purification unit, the compressed and purified air distilled into at least a nitrogen-rich fraction and oxygen-rich fraction within a distillation column unit having at least a higher pressure column and a lower pressure column, the lower pressure column being operatively associated with the higher pressure column in a heat transfer relationship and connected to the higher pressure column such that a crude liquid oxygen stream produced in the higher pressure column is introduced into and further refined in the lower pressure column; and the cryogenic rectification process being conducted such that an oxygen and argon containing vapor stream from the lower pressure column is introduced to an argon column configured to produce an argon-rich fraction stream which is condensed in an argon condenser to produce an argon product; the cryogenic rectification process being conducted such that the crude liquid oxygen stream and a liquid air stream are produced that contain oxygen and nitrogen, the crude liquid oxygen stream having a higher oxygen content than the compressed and purified air and the liquid air stream having a lower oxygen content than the crude liquid oxygen stream and an argon content no less than the compressed and purified air after purification in the purification unit; introducing a portion of the crude liquid oxygen stream into the argon condenser after having been valve expanded; subcooling the liquid air stream while in the argon condenser through indirect heat exchange with a portion of the crude liquid oxygen stream while in the argon condenser; introducing the subcooled liquid air stream as a liquid stream into the lower pressure column at a column location above that at which the crude liquid oxygen stream or any portion thereof is introduced into the lower pressure column; and producing a liquid phase stream and a vapor phase stream from the crude liquid oxygen stream by indirectly exchanging heat with the argon-rich fraction stream within the argon condenser thereby condensing the argon-rich fraction stream and introducing the liquid phase stream and the vapor phase stream into the lower pressure column; wherein the argon condenser functions to both subcool the liquid air stream and condense argon-rich fraction stream via indirect heat exchange with the crude liquid oxygen stream.