PREPARATION METHOD FOR SINGLE-ION NANOCONDUCTOR

摘要

A preparation method for a single-ion nanoconductor, comprising: preparing a solution of a nano sol by a hydrolysis reaction, where the nano sol is at least one selected from a titanium sol, an aluminum sol, a silicon sol, and a zirconium sol; adding a silane coupling agent having a C=C group, heating in a protective gas, and reacting to produce a solution of a C=C group-grafted nano sol; adding methyl methacrylate monomer, acrylic monomer, and an initiator into the solution of the C=C group-grafted nano sol, heating, and reacting to produce a nano sol -P(AA-MMA) complex; heating in a liquid-phase medium in a reaction autoclave and pressurizing for a reaction, where the heating temperature is between 145 °C and 200 °C and the pressure is between 1 MPa and 2 MPa, producing a fully dehydroxylated crystalline oxide nanoparticle -P(AA-MMA) complex, where the oxide nanoparticle is at least one among the oxides of titanium, aluminum, silicon, and zirconium; and, adding the oxide nanoparticle -P(AA-MMA) and lithium hydroxide into an organic solvent for mixing and heating to produce a transparent and clear liquid dispersion of the single-ion nanoconductor.