EMM-26, A NOVEL SYNTHETIC CRYSTALLINE MATERIAL, ITS PREPARATION, AND ITS USE

摘要

EMM-26 is a novel synthetic crystalline material having a single crystalline phase with a unique T-atom connectivity and X-ray diffraction pattern which identify it as a novel material. EMM-26 has a two-dimensional pore system defined by 10-membered rings of tetrahedrally coordinated atoms having pore dimensions of ˜6.3 Åט3.2 Å. EMM-26 may be prepared with a organic structure directing agent, such as 1,6-bis(N-methylpyrrolidinium) hexane dications and/or 1,6-bis(N-methylpiperidinium) hexane dications. EMM-26 may be used in organic compound conversion and/or sorptive processes.

主权项

1. A synthetic crystalline material having a framework of tetrahedral atoms (T) connected by bridging atoms, the tetrahedral atom framework being defined by connecting the nearest tetrahedral (T) atoms in the manner shown in Table 1:TABLE 1T1T2, T45, T47, T95T2T1, T20, T29, T42T3T42, T45, T88, T94T4T5, T8, T20, T34T5T4, T6, T17, T18T6T5, T7, T63, T65T7T6, T15, T28, T39T8T4, T39, T63, T72T9T10, T13, T32, T59T10T9, T11, T24, T57T11T10, T12, T55, T58T12T11, T22, T30, T40T13T9, T40, T55, T78T14T15, T19, T31, T95T15T7, T14, T16, T94T16T15, T17, T76, T78T17T5, T16, T29, T39T18T5, T20, T34, T96T19T14, T39, T58, T76T20T2, T4, T18, T26T21T22, T25, T33, T90T22T12, T21, T23, T89T23T22, T24, T70, T72T24T10, T23, T27, T40T25T21, T40, T65, T70T26T20, T60, T81, T83T27T24, T48, T67, T92T28T7, T60, T61, T79T29T2, T17, T43, T74T30T12, T53, T69, T84T31T14, T46, T77, T94T32T9, T56, T57, T87T33T21, T51, T71, T89T34T4, T18, T64, T82T35T56, T58, T71, T72T36T64, T65, T77, T78T37T46, T47, T82, T83T38T51, T52, T87, T88T39T7, T8, T17, T19T40T12, T13, T24, T25T41T69, T73, T92, T93T42T2, T3, T60, T96T43T29, T44, T47, T75T44T43, T45, T74, T82T45T1, T3, T44, T46T46T31, T37, T45, T80T47T1, T37, T43, T73T48T27, T49, T52, T68T49T48, T50, T67, T87T50T49, T51, T91, T93T51T33, T38, T50, T85T52T38, T48, T91, T96T53T30, T54, T58, T85T54T53, T55, T71, T84T55T11, T13, T54, T56T56T32, T35, T55, T68T57T10, T32, T59, T73T58T11, T19, T35, T53T59T9, T57, T66, T92T60T26, T28, T42, T95T61T28, T62, T65, T80T62T61, T63, T77, T79T63T6, T8, T62, T64T64T34, T36, T63, T75T65T6, T25, T36, T61T66T59, T69, T86, T88T67T27, T49, T68, T72T68T48, T56, T67, T70T69T30, T41, T66, T90T70T23, T25, T68, T71T71T33, T35, T54, T70T72T8, T23, T35, T67T73T41, T47, T57, T86T74T29, T44, T75, T78T75T43, T64, T74, T76T76T16, T19, T75, T77T77T31, T36, T62, T76T78T13, T16, T36, T74T79T28, T62, T80, T83T80T46, T61, T79, T81T81T26, T80, T82, T96T82T34, T37, T44, T81T83T26, T37, T79, T93T84T30, T54, T85, T88T85T51, T53, T84, T86T86T66, T73, T85, T87T87T32, T38, T49, T86T88T3, T38, T66, T84T89T22, T33, T90, T93T90T21, T69, T89, T91T91T50, T52, T90, T92T92T27, T41, T59, T91T93T41, T50, T83, T89T94T3, T15, T31, T95T95T1, T14, T60, T94T96T18, T42, T52, T81