Adhesive composition and adhesive containing the same

摘要

It is an object of the present invention to provide adhesive compositions having excellent flexibility, rubber elasticity, mechanical properties, heat resistance and low-temperature properties.;An adhesive composition of the invention includes 10 to 70 parts by weight of a soft polypropylene resin composition (X) which includes 40 to 98 wt % of a propylene copolymer (A) satisfying the following requirements (A1) to (A8) and 2 to 60 wt % of a crystalline isotactic polypropylene (B) satisfying the following requirements (B1) to (B3), and 30 to 90 parts by weight of a tackifier (C) (wherein the total of the component (X) and the component (C) is 100 parts by weight), wherein (A1) Shore A hardness: 20 to 90; (A2) the copolymer comprises a copolymer with C3 units at 51 to 90 mol %, C2 units at 7 to 24 mol % and C4-20 α-olefin units at 3 to 25 mol %; (A3) Mw/Mn: 1.2 to 3.5; (A4) mm: 85 to 99.9%; (A5) value B: 0.8 to 1.3; (A6) 2,1-insertion ratio: less than 1%; (A7) Tg: −10° C. to −50° C.; (A8) MFR (230° C.): 0.5 to 500 g/10 min; (B1) Tm: 100 to 175° C.; (B2) mmmm: 90 to 99.8%; (B3) MFR (230° C.): 0.1 to 100 g/10 min.

主权项

1. A hot melt adhesive consisting of:
10 to 70 parts of a polypropylene resin composition (X); 30 to 90 parts of at least one tackifier (C) selected from the group consisting of natural rosins, modified rosins, polyterpene resins, synthetic petroleum resins, coumarone resins, phenolic resins, xylene resins, styrene resins, and isoprene resins, wherein the total of the component (X) and the component (C) is 100 parts by weight; and optionally at least one first additive selected from the group consisting of a flow modifier, an inorganic filler, an antioxidant and a weathering stabilizer, wherein the polypropylene resin composition (X) consists of:
40 to 98 wt. % of a propylene copolymer (A) satisfying the following requirements (A1) to (A8):
(Al) the Shore A hardness is in the range of 20 to 90;(A2) the propylene copolymer is a propylene/ethylene/C4-20 α-olefin copolymer comprising: 51 to 90 mol. % of structural units derived from propylene, 7 to 24 mol. % of structural units derived from ethylene and 3 to 25 mol. % of structural units derived from an α-olefin having 4 to 20 carbon atoms, wherein the total of the structural units from propylene, the structural units from ethylene and the structural units from an α-olefin having 4 to 20 carbon atoms is 100 mol. %;(A3) the ratio, of the weight average molecular weight, Mw, to the number average molecular weight, Mn, according to gel permeation chromatography, GPC, is 1.2 to 3.5;(A4) the isotactic triad fraction, ram, calculated by 13C-NMR is 85 to 99.9%:(A5) the value B defined by Formula below is 0.8 to 1.3:B=MOE2⁢⁢MO·ME(1)wherein Moe is a molar fraction of the total of propylene-ethylene sequences and C4 or higher α-olefin-ethylene sequences to all the dyad sequences, Mo is a total of molar fractions of propylene and the C4 or higher α-olefin, and ME, is a molar fraction of ethylene;
(A6) the ratio of 2,1-insertions of propylene monomers in all propylene insertions is less than 1% according to 13C-NMR;(A7) the glass transition temperature, Tg, is observed in the range of −10° C. to −50° C.;(A8) MFR, as measured in accordance with ASTM D 1238 at 230° C. under a load of 2.16 kg, is 0.5 to 500 g/10 min;2 to 60 wt. % of a crystalline isotactic polypropylene (B) satisfying the following requirements (B1) to (B3):
(B1) the melting point, Tm, is in the range of 100 to 175° C. as measured by DSC wherein the polymer is held at 200° C. for 10 minutes in a differential scanning calorimeter, DSC, cooled to −20° C. at a temperature decreasing rate of 10° C./min, held at −20° C. for 1 minute, and heated at a temperature increasing rate of 10° C./min;(B2) the isotactic pentad fraction, mmmm, is 90 to 99.8%; and(B3) the melt flow rate, MFR, as measured in accordance with ASTM D 1238 at 230° C. under a load of 2.16 kg, is 0.1 to 100 g/10 min; and optionally at least one second additive selected from the group consisting of weathering stabilizer, heat stabilizer, antistatic agent, anti-slip agent, antiblocking agent, antifogging agent, nucleating agent, lubricant, pigment, dye, plasticizer, anti-aging agent, hydrochloric acid absorber, antioxidant and copper inhibitor.