发明名称 Cathode active material and lithium secondary battery containing them
摘要 Provided is a non-aqueous electrolyte-based, high-power lithium secondary battery having a long service life and superior safety at both room temperature and high temperature, even after repeated high-current charging and discharging. The battery comprises a mixture of a lithium/manganese spinel oxide having a substitution of a manganese (Mn) site with a certain metal ion and a lithium/nickel/cobalt/manganese composite oxide, as a cathode active material.
申请公布号 US9269951(B2) 申请公布日期 2016.02.23
申请号 US201414537979 申请日期 2014.11.11
申请人 LG Chem, Ltd. 发明人 Ryu Ji Heon;Kim Min Su;Hyun Jung Eun;Lee Jaepil;Lee Eun Ju;Shin Youngjoon
分类号 H01M4/36;H01M10/052;H01M4/505;H01M4/525;H01M10/0525;H01M4/02 主分类号 H01M4/36
代理机构 Lerner, David, Littenberg, Krumholz & Mentlik, LLP 代理人 Lerner, David, Littenberg, Krumholz & Mentlik, LLP
主权项 1. A cathode active material for a lithium secondary battery, comprising a mixture of a lithium/manganese spinel oxide represented by Formula I and a lithium/nickel/cobalt/manganese oxide represented by Formula II: Li1+xMn2-yMyO4  (I) Li1+zNibMncCo1−(b+c)O2  (II) wherein, M is a metal having an oxidation number of 2 to 3; 0<x≦0.2; 0<y≦0.2; 0.1≦z≦0.1; 0.45≦b≦65; 0.2≦c≦0.4; and 0.65≦b+c≦0.85 wherein the mixing ratio of the lithium/manganese spinel oxide of Formula I to the lithium/nickel/cobalt/manganese composite oxide of Formula II is in the range of 10:90 to 90:10 (w/w); and wherein the cathode active material exhibits the life characteristics that the capacity at 300 cycles is more than 80% relative to the initial capacity.
地址 KR