发明名称 |
Manganese phosphates and related electrode active materials |
摘要 |
The invention provides electrode active materials comprising lithium or other alkali metals, manganese, a +3 oxidation state metal ion, and optionally other metals, and a phosphate moiety. Such electrode active materials include those of the formula:
AaMnbMIcMIIdMIIIePO4
wherein
(a) A is selected from the group consisting of Li, Na, K, and mixtures thereof, and 0<a≦1;(b) 0<b≦1;(c) MI is a metal ion in the +3 oxidation state, and 0<c<0.5;(d) MII is metal ion, a transition metal ion, a non-transition metal ion or mixtures thereof, and 0≦d<0.5;(e) MIII is a metal ion in the +1 oxidation state and 0<e<0.5; and wherein A, Mn, MI, MII, MIII, PO4, a, b, c, d and e are selected so as to maintain electroneutrality of said compound. |
申请公布号 |
US9269955(B2) |
申请公布日期 |
2016.02.23 |
申请号 |
US201314071884 |
申请日期 |
2013.11.05 |
申请人 |
Valence Technology Inc. |
发明人 |
Huang Haitao;Saidi M. Yazid |
分类号 |
H01M4/58;H01B1/02;C01B25/26;H01M10/052;H01M10/0525 |
主分类号 |
H01M4/58 |
代理机构 |
|
代理人 |
Williams Roger A. |
主权项 |
1. An electrode active material of the formula:
AaMnbMIcMIIdMIIIePO4 wherein:
(a) A is Li, and a is 1; (b) 0<≦1; (c) MI is a metal ion in the +3 oxidation state, and 0<c≦0.5; (d) MII is metal ion, a transition metal ion, a non-transition metal ion or mixtures thereof, and 0<d≦0.5; (e) MIII is Li and 0<e≦0.5; and wherein A, Mn, MI, MII, MII, PO4, a, b, c, d and e are selected so as to maintain electroneutrality of said electrode active material. |
地址 |
Las Vegas NV US |