发明名称 Golf ball composition and golf ball
摘要 A golf ball having a good rebound and excellent flight performance can be obtained using a golf ball composition which includes a diene polymer containing not more than 1.5% of components having a molecular weight of 30,000 or less.
申请公布号 US9254420(B2) 申请公布日期 2016.02.09
申请号 US201213419871 申请日期 2012.03.14
申请人 BRIDGESTONE SPORTS CO., LTD.;BRIDGESTONE CORPORATION 发明人 Takeichi Hideo;Ohira Takashi;Ozawa Yuichiro;Nakajima Tsuyoshi;Tamaki Satoru;Yamagata Yusuke;Mori Teppei
分类号 C08L9/00;A63B37/00;A63B37/04;C08F136/06;C08F4/54;C08F4/6592;A63B45/00 主分类号 C08L9/00
代理机构 Sughrue Mion, PLLC 代理人 Sughrue Mion, PLLC
主权项 1. A method for preparing a golf ball composition comprising: a step of producing a diene polymer (A) including not more than 1.5% of components having a molecular weight of 30,000 or less; which is synthesized using as a catalyst at least one type of complex selected from the group consisting of metallocene complexes of general formulae (I) and (II) below, and half-metallocene cation complexes of general formula (III) below, and using an organolaluminum compound of the general formula AIRR′R″ wherein R and R′ are each independently a C1-10 hydrocarbon group, a chlorine or a hydrogen atom, and R″ is a C1-10 hydrocarbon group in an amount of from 83.3 to 500 moles per mole of the metallocene complex as a co-catalyst; wherein the center metal M in general formulae (I), (II) and (III) is gadolinium: wherein in formula (I), each occurrence of CpR is a substituted or unsubstituted indenyl; Ra to Rf are each independently an alkyl group of 1 to 3 carbons or a hydrogen atom; L is a neutral Lewis base; and w is an integer from 0 to 3; wherein in formula (II), each occurrence of CpR is a substituted or unsubstituted indenyl; X′ is a hydrogen atom, a halogen atom, an alkoxide group, a thiolate group, an amide group, a silyl group or a hydrocarbon group of 1 to 20 carbons; L is a neutral Lewis base; and w is an integer from 0 to 3; wherein in formula (III), CpR′ is a substituted or unsubstituted cyclopentadienyl, indenyl or fluorenyl; X is a hydrogen atom, a halogen atom, an alkoxide group, a thiolate group, an amide group, a silyl group or a hydrocarbon group of 1 to 20 carbons; L is a neutral Lewis base; w is an integer from 0 to 3; and [B]− is a non-coordinating anion; and then a step of compounding the diene polymer (A) with an unsaturated carboxylic acid and/or a metal salt thereof (B), and an organic peroxide (D) to make up the golf ball composition.
地址 Tokyo JP