发明名称 |
Multi-metallic ziegler-natta procatalysts and cataysts prepared therefrom for olefin polymerizations |
摘要 |
Novel catalyst compositions comprising three or more transition metals are effective in increasing catalyst efficiency, reducing polydispersity, and increasing uniformity in molecular weight distribution when used in olefin, and particularly, linear low density polyethylene (LLDPE), polymerizations. The resulting polymers may be used to form differentiated products including, for example, films that may exhibit improved optical and mechanical properties. |
申请公布号 |
US9255160(B2) |
申请公布日期 |
2016.02.09 |
申请号 |
US201214116070 |
申请日期 |
2012.05.23 |
申请人 |
Dow Global Technologies LLC |
发明人 |
Desjardins Sylvie;Demirors Mehmet;Donkers Ellen;Fontaine Philip P.;Serrat Cristina |
分类号 |
C08F4/685;C08F10/02;C08F210/16 |
主分类号 |
C08F4/685 |
代理机构 |
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代理人 |
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主权项 |
1. A process to prepare a multi-metallic procatalyst comprising
(a) reacting a hydrocarbon-soluble organomagnesium compound or complex thereof and an active non-metallic or metallic halide to form a halogenated magnesium support; (b) contacting the magnesium halide support with a conditioning compound containing an element selected from the group consisting of boron, aluminum, gallium, indium and tellurium under conditions sufficient to form a conditioned magnesium halide support; (c) contacting the conditioned magnesium halide support and a compound containing, as a first metal, titanium, to form a supported titanium compound; (d) contacting the supported titanium compound and a second metal and a third metal independently selected from the group consisting of zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, and tungsten, provided that the second metal and the third metal are not the same; and further provided that the molar ratio of the magnesium to a combination of the titanium and the second and third metals ranges from 30:1 to 5:1; under conditions sufficient to form a multi-metallic procatalyst. |
地址 |
Midland MI US |