发明名称 |
Method of preparing aromatic carbonate from dialkyl carbonate |
摘要 |
A method of preparing an aromatic carbonate includes reacting a dialkyl carbonate with an aromatic alcohol in the presence of a catalyst represented by Formula 1. With the method, aromatic carbonate can be prepared from a dialkyl carbonate in high yield using a catalyst capable of increasing initial reactivity of the dialkyl carbonate.;wherein X1 and X2 are the same or different and are each independently M—OR1)3 or; wherein M is a Group IV transition metal, R1 and R2 are the same or different and are each independently a substituted or unsubstituted C1 to C20 hydrocarbon group, and R3 is a substituted or unsubstituted C5 to C20 cyclic alkylene group or arylene group. |
申请公布号 |
US9255060(B2) |
申请公布日期 |
2016.02.09 |
申请号 |
US201514699143 |
申请日期 |
2015.04.29 |
申请人 |
Samsung SDI Co., Ltd. |
发明人 |
Lee Seung Hwan;Kim Dong Baek;Bae Jin Yong;Song Su Jeong;Lee Ju Hyun |
分类号 |
C07C68/06;B01J31/22 |
主分类号 |
C07C68/06 |
代理机构 |
Additon, Higgins & Pendleton, P.A. |
代理人 |
Additon, Higgins & Pendleton, P.A. |
主权项 |
1. A method of preparing an aromatic carbonate, comprising: reacting a dialkyl carbonate with an aromatic alcohol in the presence of a catalyst represented by Formula 1: wherein X1 and X2 are the same or different and are each independently M—(OR1)3 or wherein M is a Group IV transition metal, R1 and R2 are the same or different and are each independently a substituted or unsubstituted C1 to C20 hydrocarbon group, and R3 is a substituted or unsubstituted C5 to C20 cyclic alkylene group or substituted or unsubstituted C5 to C20 arylene group. |
地址 |
Yongin-si KR |