| 摘要 |
Provided is a mononuclear iron complex that comprises an iron-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound.;;In formula (1), R1-R6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R1-R3 and one of R4-R6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4. |
| 主权项 |
1. A mononuclear iron complex having formula (1): wherein R1 to R6 are each independently hydrogen, or an alkyl, aryl, aralkyl, organoxy, monoorganoamino, diorganoamino, monoorganophosphino, diorganophosphino, monoorganosilyl, diorganosilyl, triorganosilyl or organothio group which may be substituted with X, or at least one pair of any one of R1 to R3 and any one of R4 to R6, taken together, represent a crosslinking substituent,
X is a halogen atom, organoxy, monoorganoamino, diorganoamino or organothio group,L is a two-electron ligand other than CO, with the proviso that when a plurality of L's are present, they may be the same or different, and when two L's are present, they may bond together,n and m are each independently an integer of 1 to 3, and n+m is 3 or 4. |
