| 摘要 |
A method for preparing a homogeneous braid-reinforced (HMR) PPTA hollow fiber membrane combines PPTA hollow tubular braids with PPTA surface separation layer. The method includes following steps of: (1) preparing the PPTA hollow tubular braids, wherein the PPTA hollow tubular braids which are made from PPTA filament yarns are woven by a two-dimensional braided method, the outer diameter of the PPTA tubular braids is 1-2 mm; (2) preparing the PPTA casting solution as the surface separation layer, wherein the 1-3 wt % PPTA resin, 0-2 wt % inorganic particles and 10-20 wt % pore-forming agents are mixed into 75-89% inorganic acid solvent, stirred for 1-3 hours at 70° C.-90° C. to form homogeneous and transparent casting solution; and (3) preparing reinforced PPTA hollow fiber membrane, wherein the casting solution as the surface separation layer is evenly coated on the surfaces of the PPTA hollow tubular braids through spinneret, and they are immersed in a coagulation bath for solidified formation. |
| 主权项 |
1. A method for preparing a homogeneous tubular braid-reinforced (HMR) PPTA hollow fiber membrane, which combines PPTA hollow tubular braids with PPTA surface separation layer, wherein the method comprises the following steps of:
(1) preparing PPTA hollow tubular braids, wherein: the PPTA hollow tubular braids which are made from PPTA filament yarns are woven by a two-dimensional braided method, and they are served as a reinforced matrix for HMR PPTA hollow fiber membranes, wherein an outer diameter of the PPTA tubular braids is 1-2 mm; a filament yam denier is 50-800 D; a woven pitch is 5-20 mm; (2) providing surface pre-treatment of the PPTA hollow tubular braids, wherein: surfaces of the hollow PPTA tubular braids are immersed in a kind of well-known neutral detergent or surfactant for 2-3 h prior to a membrane preparation, and then repeatedly flushed with clean water and totally dried for further use, wherein the neutral detergent is laundry detergent; the surfactant is sodium dodecylsulphate or sodium dodecylsulfate; (3) preparing PPTA casting solution as the surface separation layer, wherein: the wholly pre-treated PPTA resin, pore-forming agents and inorganic particles are mixed into an inorganic acid solvent, stirred for 1-3 hours at 70° C.-90° C. to form homogeneous and transparent casting solution, wherein components of casting solution and a mass fraction of surface separation layer are:the PPTA resin1-3 wt %the pore-forming agents10-20 wt % the inorganic particles0-2 wt %the inorganic acid solution75-89 wt %, totally 100%; wherein a logarithmic specific concentration viscosity of the PPTA resin is 4-10 dL/g; wherein the pore-forming agents are water-soluble macromolecule, which is polyethylene glycol (PEG) with an average molecular weight of 600-20000, or polyvinylpyrrolidone (PVP) with an average molecular weight of 10000-100000, or a mixture of the PEG and the PVP with a ratio of (4:1)-(10:1) by weight; wherein the inorganic particles are selected from a group consisting of silicon dioxide, titanium dioxide and graphene oxide; wherein the inorganic acid solution is concentrated sulfuric acid with a mass concentration at a range of 98-106 wt %; and (4) preparing reinforced PPTA hollow fiber membrane, wherein: the casting solution as the surface separation layer is evenly coated on the surfaces of the PPTA hollow tubular braids through spinneret, and then they are passed through an air bath of 1-10 cm under the winding tension, afterwards they are immersed in a coagulation bath of 0-50° C. for solidified formation, so as to obtain the as-spun HMR PPTA hollow fiber membranes, wherein a spinning temperature is kept at 60-80° C., a speed of winding tension is 1-30 m/h, a coagulation bath is a sulfuric acid solution with a mass fraction of 0-30%. |
