发明名称 |
METHOD FOR CONTINUOUSLY PRODUCING HIGH-MOLECULAR-WEIGHT POLYCARBONATE RESIN |
摘要 |
<p>Provided is an improved method for continuously producing a high molecular weight polycarbonate resin by subjecting an aromatic polycarbonate prepolymer and an aliphatic diol compound to a linking and highly polymerizing reaction, wherein even an aliphatic diol compound having a comparatively low boiling point can be allowed to efficiently contribute to the linking and highly polymerizing reaction, and a high molecular weight polycarbonate resin of superior quality can be produced both economically and advantageously. Provided is a method which comprises producing an aromatic polycarbonate prepolymer by a polycondensation reaction between an aromatic dihydroxy compound and a diester carbonate, adding thereto an aliphatic diol compound having an aliphatic group that bonds to a terminal hydroxyl group to obtain a prepolymer mixture, and subjecting the resulting prepolymer mixture to a linking and highly polymerizing reaction under a reduced pressure condition, wherein the aliphatic diol compound is added at a pressure exceeding 200 torr, and then, the prepolymer mixture is subjected to a linking and highly polymerizing reaction before the terminal hydroxyl group concentration of the aromatic polycarbonate prepolymer in the prepolymer mixture reaches 2000 ppm.</p> |
申请公布号 |
EP2851385(A4) |
申请公布日期 |
2016.01.06 |
申请号 |
EP20130790222 |
申请日期 |
2013.05.14 |
申请人 |
MITSUBISHI GAS CHEMICAL COMPANY, INC. |
发明人 |
ISAHAYA, YOSHINORI;HIRASHIMA, ATSUSHI;HARADA, HIDEFUMI;ITO, MAKI;HAYAKAWA, JUN-YA;ISOBE, TAKEHIKO;TOKUTAKE, TAICHI;SHINKAI, YOUSUKE |
分类号 |
C08G64/30;C08G64/20 |
主分类号 |
C08G64/30 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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