发明名称 Method of manufacturing fluoride phosphor
摘要 A method of manufacturing a fluoride phosphor includes mixing a first solution which contains at least Mn and F, a second solution which contains at least K and F, and a third solution which contains at least Si and F to form phosphor cores whose composition is represented by a formula K2[M1-aMn4+aF6] wherein a satisfies 0<a<0.2, and M includes at least one selected from group-IV elements of Ti, Zr, and Hf and group IVB elements of Si, Ge, Sn. The phosphor cores and a fourth solution containing a reducing agent are mixed to form a surface region on each of the phosphor cores so that a concentration of tetravalent Mn on the surface region of one of the phosphor cores is lower than in an inner region of the one of the phosphor cores.
申请公布号 US9222017(B2) 申请公布日期 2015.12.29
申请号 US201514804337 申请日期 2015.07.21
申请人 NICHIA CORPORATION 发明人 Yoshida Tomokazu
分类号 C09K11/61;H01L33/50;H01L33/00;H01L33/06;C09K11/67;C09K11/02;H01L33/54;G02F1/1335 主分类号 C09K11/61
代理机构 Mori & Ward, LLP 代理人 Mori & Ward, LLP
主权项 1. A method of manufacturing a fluoride phosphor, comprising: mixing a first solution which contains at least Mn and F, a second solution which contains at least K and F, and a third solution which contains at least Si and F to form phosphor cores whose composition is represented by a formula K2[M1-aMn4+aF6] wherein a satisfies 0<a<0.2, and M comprises at least one selected from group-IV elements of Ti, Zr, and Hf and group IVB elements of Si, Ge, Sn; and mixing the phosphor cores and a fourth solution containing a reducing agent to form a surface region on each of the phosphor cores so that a concentration of tetravalent Mn on the surface region of one of the phosphor cores is lower than in an inner region of the one of the phosphor cores.
地址 Anan-shi JP