发明名称 Pyrolysis Tar Upgrading Using Recycled Product
摘要 The invention relates to a process for upgrading pyrolysis tar in the presence of a utility fluid. The utility fluid contains 1-ring and/or 2-ring aromatics and has a final boiling point ≦430° C. The invention also relates to the upgraded pyrolysis tar, and to the use of the upgraded pyrolysis tar, e.g., for fuel oil blending.
申请公布号 US2015368570(A1) 申请公布日期 2015.12.24
申请号 US201514683511 申请日期 2015.04.10
申请人 ExxonMobil Chemical Patents Inc. 发明人 Beech, JR. James H.;Koc-Karabocek Reyyan;Lewis William E.;Xu Teng
分类号 C10G69/06;C10G47/00;C10G45/58;C10G45/02;C10G45/44 主分类号 C10G69/06
代理机构 代理人
主权项 1. A hydrocarbon conversion process, comprising: (a) providing a pyrolysis feedstock comprising ≧10.0 wt. % hydrocarbon based on the weight of the pyrolysis feedstock; (b) pyrolysing the pyrolysis feedstock to produce a pyrolysis effluent comprising tar and ≧1.0 wt. % of C2 unsaturates, based on the weight of the pyrolysis effluent; (c) separating at least a portion of the tar from the pyrolysis effluent, wherein the separated tar contains ≧90 wt. % of the pyrolysis effluent's molecules having an atmospheric boiling point of ≧290° C.; (d) providing a utility fluid, the utility fluid comprising 1-ring and/or 2-ring aromatics, in an amount ≧25.0 wt. % based on the weight of the utility fluid, the utility fluid having a final boiling point ≦430° C.; (e) providing a treat gas comprising molecular hydrogen; (f) hydroprocessing at least a portion of the separated tar in the presence of (i) the treat gas and (ii) the utility fluid under catalytic hydroprocessing conditions at a utility fluid:tar weight ratio in the range of 0.05 to 4.0, to produce a hydroprocessed product; (g) separating a product overhead mixture and a product bottoms mixture from the hydroprocessed product, wherein (i) the product overhead mixture comprises at least a portion of any un-reacted treat gas and (ii) the product bottoms mixture comprising hydroprocessed tar; (h) separating from the product bottoms mixture (i) a product vapor stream, (ii) a product liquid stream, and (iii) a side stream, the side stream having a final boiling point ≦430° C. and comprising 1-ring and/or 2-ring aromatics, in an amount ≧25.0 wt. % based on the weight of the side stream; and (i) conducting a portion of the side stream to step (d), wherein the utility fluid comprises ≧10.0 wt. % of the side stream, based on the weight of the utility fluid.
地址 Baytown TX US