发明名称 PA-MXDT/ZT COPOLYMERS
摘要 The invention related to a process for the production of a PA-MXDT/ZT polyamide copolymer comprising the following steps: •i. providing a solid MXDT/ZT salt, wherein MXD is meta-xylylenediamine, T is terephthalic acid, Z is a linear aliphatic diamine having from 2 to 12 carbon atoms and wherein amount of Z is from 5 to 40 mole % with respect to the total amount of MXD and Z units in the copolymer and wherein the MXDT/ZT salt is provided by dosing of liquid diamines MXD and Z to a powder of terephthalic acid; •ii. heating the solid MXDT/ZT salt to a first condensation temperature (Tc1) thereby condensing the salt in solid state to produce a solid polyamide copolymer, wherein Tc1 is below the melting temperature (Tm-salt) of said salt. The invention further relates to a PA-MXDT/ZT polyamide copolymer, wherein MXD is meta-xylylenediamine, T is terephthalic acid, Z is a linear aliphatic diamine having from 2 to 12 carbon atom, Z is from 5 to 40 mole % with respect to the total of MXD and Z units in the copolymer.
申请公布号 US2015368399(A1) 申请公布日期 2015.12.24
申请号 US201414763601 申请日期 2014.01.30
申请人 DSM IP ASSETS B.V. 发明人 RULKENS Rudy;CUYPERS Theo Joseph;VANDEN POEL Geert Adelina Rudolf;GROLMAN Eric;KIERKELS Renier Henricus Maria
分类号 C08G69/30;C08G69/26 主分类号 C08G69/30
代理机构 代理人
主权项 1. Process for the production of a PA-MXDT/ZT polyamide copolymer comprising the following steps: i. providing a solid MXDT/ZT salt, wherein MXD is meta-xylylenediamine, T is terephthalic acid, Z is a linear aliphatic diamine having from 2 to 12 carbon atoms and wherein amount of Z is from 5 to 40 mole % with respect to the total amount of MXD and Z units in the copolymer and wherein the MXDT/ZT salt is provided by dosing of liquid diamines MXD and Z to a powder of terephthalic acid; ii. heating the solid MXDT/ZT salt to a first condensation temperature (Tc1) thereby condensing the salt in solid state to produce a solid polyamide copolymer, wherein Tc1 is below the melting temperature (Tm-salt) of said salt.
地址 Heerlen NL