发明名称 PHOTO-CURABLE COATING COMPOSITION AND COATED ARTICLE
摘要 A photo-curable coating composition comprising (1) a polyfunctional (meth)acrylic monomer, (2) a photopolymerization initiator, and (3) a specific hydroxyphenyltriazine base UV absorber has high mar resistance and long-term weather resistance.
申请公布号 US2015368474(A1) 申请公布日期 2015.12.24
申请号 US201514746359 申请日期 2015.06.22
申请人 Shin-Etsu Chemical Co., Ltd. 发明人 HIGUCHI Koichi;AOKI Yukimasa
分类号 C09D4/00;C09D7/12;C09D5/00 主分类号 C09D4/00
代理机构 代理人
主权项 1. A photo-curable coating composition comprising (1) a polyfunctional (meth)acrylic monomer, (2) a photopolymerization initiator, and (3) a hydroxyphenyltriazine base UV absorber having the general formula (1): wherein Y1 and Y2 are each independently a substituent having the general formula (2): wherein * designates a bonding site, r is 0 or 1, R1, R2 and R3 are each independently hydrogen, or hydroxyl, C1-C20 alkyl, C4-C12 cycloalkyl, C2-C20 alkenyl, C1-C20 alkoxy, C4-C12 cycloalkoxy, C2-C20 alkenyloxy, C7-C20 aralkyl, halogen, —C≡N, C1-C5 haloalkyl, —SO2R′, —SO3H, —SO3M wherein M is an alkali metal, —COOR′, —CONHR′, —CONR′R″, —OCOOR′, —OCOR′, —OCONHR′, (meth)acrylamino, (meth)acryloxy group, optionally substituted C6-C12 aryl or optionally substituted C3-C12 heteroaryl group, wherein R′ and R″ are independently hydrogen, C1-C20 alkyl, C4-C12 cycloalkyl, optionally substituted C6-C12 aryl or optionally substituted C3-C12 heteroaryl group, X is a divalent, straight or branched, saturated hydrocarbon residue which may be separated by at least one atom selected from oxygen, nitrogen, sulfur, and phosphorus, T is a urethane group: —O—(C═O)—NH—, Q is a divalent, straight or branched, saturated hydrocarbon residue which may be separated by at least one atom selected from oxygen, nitrogen, sulfur, and phosphorus, and P is a (meth)acryloxy group.
地址 Tokyo JP