发明名称 Process for activating cobalt catalysts
摘要 A particulate pre-reduction cobalt supported Fischer-Tropsch synthesis catalyst precursor which comprises a catalyst support impregnated with cobalt, is treated with a pure hydrogen reducing gas, at a first specific feed gas space velocity, SV1, and at a first heating rate, HR1, to obtain a partially reduced precursor. The support contains reducible cobalt oxide in a calcined state and having a formula-unit in which each mole of cobalt atoms is associated with more than 4/3 moles of oxygen atoms and displaying a reducible cobalt oxide specific surface area at least equal to that of Co3O4 spinel. The partially reduced precursor is then treated with a pure hydrogen reducing gas, at a second specific feed gas space velocity, SV2, and at a second heating rate, HR2, to obtain an activated supported Fischer-Tropsch catalyst, with SV2<=SV1 and/or HR2>=HR1; however, when SV2=SV1, HR2<>HR1 and when HR2=HR1, SV2<>SV1.
申请公布号 US7592289(B2) 申请公布日期 2009.09.22
申请号 US20050480778 申请日期 2005.04.11
申请人 SASOL TECHNOLOGY (PROPRIETARY) LIMITED;ENGELHARD DE MEERN B.V. 发明人 VAN BERGE PETER JACOBUS;VISAGIE JACOBUS LUCAS;VAN DE LOOSDRECHT JAN;VAN DER WALT TJAART JURGENS;SOLLIE JOHAN COENRAAD;SOLLIE-BREUR, LEGAL REPRESENTATIVE SYLVIA;VELTMAN HANS MARCEL
分类号 B01J23/00;B01J23/89;B01J23/40;B01J23/42;B01J23/75;B01J37/08;B01J37/18 主分类号 B01J23/00
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